tetradecyl (pentafluorophenyl)thionocarbonate

Base Information

• Chemical Name: tetradecyl (pentafluorophenyl)thionocarbonate
• CAS No.: 140479-90-9
• Molecular Formula: C₂₁H₂₉F₅O₂S
• Molecular Weight: 440.518
• Mol file: 140479-90-9.mol

Synonyms:tetradecyl (pentafluorophenyl)thionocarbonate

Chemical Property of tetradecyl (pentafluorophenyl)thionocarbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetradecyl (pentafluorophenyl)thionocarbonate

There total 2 articles about tetradecyl (pentafluorophenyl)thionocarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1-Tetradecanol (112-72-1) + pentafluorophenoxythiocarbonyl chloride (135192-53-9) → tetradecyl (pentafluorophenyl)thionocarbonate (140479-90-9)

Guidance literature:

With pyridine; dmap; In benzene; for 4h;

DOI:10.1016/S0040-4020(01)86502-9

Reference yield:

2,3,4,5,6-pentafluorophenol (771-61-9) → tetradecyl (pentafluorophenyl)thionocarbonate (140479-90-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / aq. 5percent NaOH / CHCl₃ / 1 h / 0 °C

2: 89 percent / pyridine / 4-dimethylaminopyridine / benzene / 4 h

With pyridine; sodium hydroxide; dmap; In chloroform; benzene;

DOI:10.1016/S0040-4020(01)86502-9

Reference yield: 95.0%

tetradecyl (pentafluorophenyl)thionocarbonate (140479-90-9) → tetradecane (629-59-4)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; 1-hydroxy-pyrrolidine-2,5-dione; In toluene; for 0.0833333h; Product distribution; Mechanism; Heating; other thionocarbonates, other solvents and reaction times, or diphenylsilane, phenylsilane, triphenylsilane in combination with benzoyl peroxide;

DOI:10.1016/S0040-4020(01)86502-9

upstream raw materials:

1-Tetradecanol

pentafluorophenoxythiocarbonyl chloride

2,3,4,5,6-pentafluorophenol

Downstream raw materials:

tetradecane

Refernces