1-aminotriphenylene

Base Information

• Chemical Name: 1-aminotriphenylene
• CAS No.: 17075-02-4
• Molecular Formula: C₁₈H₁₃N
• Molecular Weight: 243.308
• Mol file: 17075-02-4.mol

Synonyms:1-aminotriphenylene

Chemical Property of 1-aminotriphenylene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-aminotriphenylene

There total 2 articles about 1-aminotriphenylene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

[1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate (189999-35-7) + 2-chloro-6-aminobenzoic acid (2148-56-3) → 1-aminotriphenylene (17075-02-4) + N-([1,1'-biphenyl]-2-yl)triphenylen-1-amine

Guidance literature:

With palladium diacetate; potassium carbonate; In 1-methyl-pyrrolidin-2-one; at 145 ℃; for 17h;

DOI:10.1021/acs.orglett.8b00071

Reference yield: 4.0%

1-nitrotriphenylene (81316-78-1) → triphenylene (217-59-4) + 1-aminotriphenylene (17075-02-4)

Guidance literature:

With hydrazine hydrate; palladium on activated charcoal; In ethanol; for 0.5h; Heating;

Reference yield: 82.0%

1-aminotriphenylene (17075-02-4) + benzoyl chloride (98-88-4) → N-(triphenylen-1-yl)benzamide

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 6h;

DOI:10.1021/acs.orglett.8b00071

upstream raw materials:

1-nitrotriphenylene

[1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate

2-chloro-6-aminobenzoic acid

Refernces

• 1、 Horaguchi, Takaaki,Klemm, L. H.,Norris, Eric S.. "Studies on Intramolecular NH-Bridging in Aromatic Compounds.". . p. 797 - 802. Retrieved 2007/10/03.