[Mo2(η5-cyclopentadienyl)2(μ-SMe)3(2,6-xylyl isocyanide)2]

Base Information

• Chemical Name: [Mo2(η5-cyclopentadienyl)2(μ-SMe)3(2,6-xylyl isocyanide)2]
• CAS No.: 870539-78-9
• Molecular Formula: BF₄*C₃₁H₃₇Mo₂N₂S₃
• Molecular Weight: 812.531
• Mol file: 870539-78-9.mol

Synonyms:[Mo2(η5-cyclopentadienyl)2(μ-SMe)3(2,6-xylyl isocyanide)2]

Chemical Property of [Mo2(η5-cyclopentadienyl)2(μ-SMe)3(2,6-xylyl isocyanide)2]

Chemical Property:

Purity/Quality:

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Technology Process of [Mo2(η5-cyclopentadienyl)2(μ-SMe)3(2,6-xylyl isocyanide)2]

There total 1 articles about [Mo2(η5-cyclopentadienyl)2(μ-SMe)3(2,6-xylyl isocyanide)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + [Mo2(η5-cyclopentadienyl)2(μ-SMe)3(μ-η1:η1-C(NHC6H3Me2)CNC6H3Me2)] → [Mo2(η5-cyclopentadienyl)2(μ-SMe)3(2,6-xylyl isocyanide)2] (870539-78-9)

Guidance literature:

In dichloromethane; under N2; a drop of HBF4*OEt2 added to cold soln. of Mo complex in CH2Cl2; stirred at -40°C for 20 min; Et2O added; filtered; ppt. washed with Et2O; detd. by (1)H NMR spectra;

DOI:10.1021/om8003702

Reference yield: 92.0%

[Mo2(η5-cyclopentadienyl)2(μ-SMe)3(2,6-xylyl isocyanide)2] (870539-78-9) + sodium hydrosulfide hydrate → [Mo2(η5-cyclopentadienyl)2(μ-SMe)3(μ-η1:η1-C(NHC6H3Me2)CNC6H3Me2)]

Guidance literature:

In tetrahydrofuran; under N2; Mo complex and NaSH (10 equiv.) in THF heated at reflux for 72h; filtered; solvent removed under vac.; washed with Et2O; elem. anal.;

DOI:10.1021/om8003702

Reference yield: 84.0%

[Mo2(η5-cyclopentadienyl)2(μ-SMe)3(2,6-xylyl isocyanide)2] (870539-78-9) → [Mo2(η5-cyclopentadienyl)(μ-SMe)3(μ-(η5-C5H4)C(NC6H3Me2)N(C6H3Me2)C)] (905309-29-7)

Guidance literature:

With NaOH; In tetrahydrofuran; (N2); refluxed for 24 h; filtered, evapd. (vac.), extd. (Et2O), evapd., washed (pentane); elem. anal.;

DOI:10.1021/om060383v

upstream raw materials:

tetrafluoroboric acid diethyl ether

Downstream raw materials:

[Mo2(η5-cyclopentadienyl)(μ-SMe)3(μ-(η5-C5H4)C(NC6H3Me2)N(C6H3Me2)C)]