(3S,4R,5R)-3,4,5-trisbenzyloxy-6-triisopropylsilanyloxy-1-trityloxyhexan-2-ol

Base Information

Chemical Name:(3S,4R,5R)-3,4,5-trisbenzyloxy-6-triisopropylsilanyloxy-1-trityloxyhexan-2-ol
CAS No.:1607820-95-0
Molecular Formula:C₅₅H₆₆O₆Si
Molecular Weight:851.211
Hs Code.:

Synonyms:(3S,4R,5R)-3,4,5-trisbenzyloxy-6-triisopropylsilanyloxy-1-trityloxyhexan-2-ol

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Chemical Property of (3S,4R,5R)-3,4,5-trisbenzyloxy-6-triisopropylsilanyloxy-1-trityloxyhexan-2-ol

Chemical Property:

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Technology Process of (3S,4R,5R)-3,4,5-trisbenzyloxy-6-triisopropylsilanyloxy-1-trityloxyhexan-2-ol

There total 6 articles about (3S,4R,5R)-3,4,5-trisbenzyloxy-6-triisopropylsilanyloxy-1-trityloxyhexan-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1607820-94-9
(3S,4R,5R)-3,4,5-tris-benzyloxy-6-triisopropylsilanyloxy-hexane-1,2-diol

: 76-83-5
trityl chloride

: 1607820-95-0
(3S,4R,5R)-3,4,5-trisbenzyloxy-6-triisopropylsilanyloxy-1-trityloxyhexan-2-ol

Guidance literature:: With dmap; triethylamine; In tetrahydrofuran; for 20h; Inert atmosphere; Reflux;

Reference yield:

: 1607820-93-8
triisopropyl-((2R,3S,4S)-2,3,4-trisbenzyloxyhex-5-enyloxy)silane

: 1607820-95-0
(3S,4R,5R)-3,4,5-trisbenzyloxy-6-triisopropylsilanyloxy-1-trityloxyhexan-2-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 4-methylmorpholine N-oxide; osmium(VIII) oxide / water; acetone; tert-butyl alcohol / 0 - 20 °C

2: triethylamine; dmap / tetrahydrofuran / 20 h / Inert atmosphere; Reflux

With dmap; osmium(VIII) oxide; 4-methylmorpholine N-oxide; triethylamine; In tetrahydrofuran; water; acetone; tert-butyl alcohol;

Reference yield:

: 108713-89-9
(2R,3R,4R)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentan-1-ol

: 1607820-95-0
(3S,4R,5R)-3,4,5-trisbenzyloxy-6-triisopropylsilanyloxy-1-trityloxyhexan-2-ol

Guidance literature:: Multi-step reaction with 5 steps

1.1: pyridine; dmap / 14 h / 20 °C

2.1: N-Bromosuccinimide / water; acetone / 0.5 h / 0 °C

3.1: potassium tert-butylate / diethyl ether / 1 h / Inert atmosphere; Reflux

3.2: 20 h / 20 °C

4.1: 4-methylmorpholine N-oxide; osmium(VIII) oxide / water; acetone; tert-butyl alcohol / 0 - 20 °C

5.1: triethylamine; dmap / tetrahydrofuran / 20 h / Inert atmosphere; Reflux

With pyridine; dmap; N-Bromosuccinimide; osmium(VIII) oxide; potassium tert-butylate; 4-methylmorpholine N-oxide; triethylamine; In tetrahydrofuran; diethyl ether; water; acetone; tert-butyl alcohol;