trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane

Base Information

Chemical Name:trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane
CAS No.:114423-65-3
Molecular Formula:C₃₂H₆₆O₃Si₂
Molecular Weight:555.045
Hs Code.:

trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-bis<dimethylthexylsilyl)oxy>cyclohexane

Synonyms:trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane

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Chemical Property of trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane

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Technology Process of trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane

There total 9 articles about trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 114423-64-2
trans,trans-3-(10'-acetoxy-6'-decenyl)-1,2-bis<(dimethylthexylsilyl)oxy>cyclohexane

: 114423-65-3
trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane

Guidance literature:: With potassium carbonate; In methanol; for 1.5h; Ambient temperature;
DOI:10.1021/jo00247a014

Reference yield:

: 4286-55-9
1-bromo-6-hexanol

: 114423-65-3
trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane

Guidance literature:: Multi-step reaction with 8 steps

1: 95 percent / Et₃N, bis(trimethylsilyl)amine / tetrahydrofuran / Ambient temperature

3: 1.) BH₃*Me₂S, 2.) 3 N NaOH, 30percent H₂O₂ / 1.) THF, RT, 3 days 2.) 1 h

4: 84 percent / CBr₄, PPh₃ / acetonitrile / 1 h / 0 °C

5: 95 percent / lutidine / CH₂Cl₂ / 0 - 20 °C

6: acetonitrile / 72 h / Heating

7: 1.) NaN(TMS)2 / 1a.) THF, 0 deg C, 1b.) reflux, 90 min, 2a.) -78 deg C, 30 min, 2b.) RT, 14 h

8: 99 percent / K₂CO₃ / methanol / 1.5 h / Ambient temperature

With sodium hydroxide; carbon tetrabromide; dimethylsulfide borane complex; lutidine; dihydrogen peroxide; sodium hexamethyldisilazane; potassium carbonate; triethylamine; triphenylphosphine; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; methanol; dichloromethane; acetonitrile;
DOI:10.1021/jo00247a014

Reference yield:

: 4224-70-8
6-bromohexanoic acid

: 114423-65-3
trans,trans-3-(10'-hydroxy-6'-decenyl)-1,2-biscyclohexane

Guidance literature:: Multi-step reaction with 9 steps

1: 98 percent / BH₃*Me₂S / tetrahydrofuran / 0 °C

2: 95 percent / Et₃N, bis(trimethylsilyl)amine / tetrahydrofuran / Ambient temperature

4: 1.) BH₃*Me₂S, 2.) 3 N NaOH, 30percent H₂O₂ / 1.) THF, RT, 3 days 2.) 1 h

5: 84 percent / CBr₄, PPh₃ / acetonitrile / 1 h / 0 °C

6: 95 percent / lutidine / CH₂Cl₂ / 0 - 20 °C

7: acetonitrile / 72 h / Heating

8: 1.) NaN(TMS)2 / 1a.) THF, 0 deg C, 1b.) reflux, 90 min, 2a.) -78 deg C, 30 min, 2b.) RT, 14 h

9: 99 percent / K₂CO₃ / methanol / 1.5 h / Ambient temperature

With sodium hydroxide; carbon tetrabromide; dimethylsulfide borane complex; lutidine; dihydrogen peroxide; sodium hexamethyldisilazane; potassium carbonate; triethylamine; triphenylphosphine; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; methanol; dichloromethane; acetonitrile;
DOI:10.1021/jo00247a014