C₂₇H₃₆O₁₁

Base Information

• Chemical Name: C₂₇H₃₆O₁₁
• CAS No.: 1384545-88-3
• Molecular Formula: C₂₇H₃₆O₁₁
• Molecular Weight: 536.576
• Mol file: 1384545-88-3.mol

Synonyms:C₂₇H₃₆O₁₁

Chemical Property of C₂₇H₃₆O₁₁

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₇H₃₆O₁₁

There total 6 articles about C₂₇H₃₆O₁₁ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

(E)-3-methoxy-4-allyloxycinnamoyl chloride (850786-96-8) + methyl (1S,3R,4R,5S,2'S,3'S)-1,3-dihydroxy-4,5-[2,3-dimethoxybutane-2,3-di(yloxy)]cyclohexane-1-carboxylate (183625-03-8) → C27H36O11 (1384545-88-3)

Guidance literature:

With pyridine; dmap; In dichloromethane; for 24h; chemoselective reaction; Reflux;

DOI:10.1039/c2ob25124h

Reference yield:

D-(-)-quinic acid (77-95-2) → C27H36O11 (1384545-88-3)

Guidance literature:

Multi-step reaction with 4 steps

1: (1S)-10-camphorsulfonic acid / 24 h / Reflux

2: pyridinium chlorochromate / dichloromethane / 16 h / 20 °C

3: sodium tris(acetoxy)borohydride; acetic acid / acetonitrile / 15 h / 20 °C

4: pyridine; dmap / dichloromethane / 24 h / Reflux

With pyridine; dmap; (1S)-10-camphorsulfonic acid; sodium tris(acetoxy)borohydride; acetic acid; pyridinium chlorochromate; In dichloromethane; acetonitrile;

DOI:10.1039/c2ob25124h

Reference yield:

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid (1135-24-6,537-98-4) → C27H36O11 (1384545-88-3)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium carbonate / acetone / 0.5 h / 20 °C

1.2: 48 h / Reflux

1.3: 2 h / Reflux

2.1: oxalyl dichloride; N,N-dimethyl-formamide / toluene / 10 h / 0 - 20 °C

3.1: pyridine; dmap / dichloromethane / 24 h / Reflux

With pyridine; dmap; oxalyl dichloride; potassium carbonate; N,N-dimethyl-formamide; In dichloromethane; acetone; toluene; 1.2: Williamson ether synthesis;

DOI:10.1039/c2ob25124h

upstream raw materials:

(E)-3-methoxy-4-allyloxycinnamoyl chloride

methyl (1S,3R,4R,5S,2'S,3'S)-1,3-dihydroxy-4,5-[2,3-dimethoxybutane-2,3-di(yloxy)]cyclohexane-1-carboxylate

(E)-3-(4-hydroxy-3-methoxyphenyl)acrylic acid

D-(-)-quinic acid

Downstream raw materials:

methyl 3-feruloyl-muco-quinate

3-O-feruloyl-muco-quinic acid

C₂₄H₃₂O₁₁

C₄₂H₅₀O₁₄