Technology Process of 3-(phenylsulfonyl)-1,3-cyclooctadiene
There total 5 articles about 3-(phenylsulfonyl)-1,3-cyclooctadiene which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
1,8-diazabicyclo[5.4.0]undec-7-ene;
In
tetrahydrofuran;
for 14h;
Yield given;
Ambient temperature;
DOI:10.1021/jo00389a019
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 89 percent / triethylamine / dimethylformamide / 12 h / 50 °C
2: 74 percent / 35percent CH3CO3H in CH3CO2H / CH2Cl2 / 1 h / Ambient temperature
3: methanesulfonyl chloride, triethylamine / tetrahydrofuran / 0 - 20 °C
4: 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) / tetrahydrofuran / 14 h / Ambient temperature
With
peracetic acid; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo00389a019
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 72 percent / Na2CO3, 37percent CH3CO3H in CH3CO2H / CH2Cl2 / 18 h / Ambient temperature
2: 89 percent / triethylamine / dimethylformamide / 12 h / 50 °C
3: 74 percent / 35percent CH3CO3H in CH3CO2H / CH2Cl2 / 1 h / Ambient temperature
4: methanesulfonyl chloride, triethylamine / tetrahydrofuran / 0 - 20 °C
5: 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) / tetrahydrofuran / 14 h / Ambient temperature
With
peracetic acid; sodium carbonate; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine;
In
tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jo00389a019
