(η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese

Base Information

• Chemical Name: (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese
• CAS No.: 458566-05-7
• Molecular Formula: C₁₆H₁₂ClMnO₄
• Molecular Weight: 358.66
• Mol file: 458566-05-7.mol

Synonyms:(η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese

Chemical Property of (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese

There total 2 articles about (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

[tricarbonyl(η(6)-4-chloroanisole)manganese]BF4 (166543-63-1) + phenylmagnesium bromide (100-58-3) → (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese (458566-05-7)

Guidance literature:

In not given; (N2); F. Balssa, V. Gagliardini, F. Rose-Munch, E. Rose, Organometallics, 1996, 15, 4373;

DOI:10.1039/c0dt01270j

Reference yield:

η6-(1-chloro-4-methoxyphenyl)tricarbonylmanganese + phenylmagnesium bromide (100-58-3) → (η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese (458566-05-7)

Guidance literature:

In not given; (Organometallics 1982, 1, 1053);

DOI:10.1021/om021017o

Reference yield: 91.0%

(η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese (458566-05-7) + para-thiocresol (106-45-6) → [Mn(CO)3(η5-1-(SC6H4-p-Me)-4-methoxy-6-phenylcyclohexadienyl)] (458566-07-9)

Guidance literature:

With NaH; catalyst: AsPh₃; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In tetrahydrofuran; under N2;

DOI:10.1021/om0202773

upstream raw materials:

[tricarbonyl(η(6)-4-chloroanisole)manganese]BF4

phenylmagnesium bromide

Downstream raw materials:

[(η5-(1-N(CH2CH2)2O-4-methoxy-6-phenylcyclohexadienyl))Mn(CO)3]

Mn(CO)3C₆H₄(CCSi(CH₃)3)(C₆H₅)OCH₃

[Mn(CO)3(η5-1-(SC6H4-p-Me)-4-methoxy-6-phenylcyclohexadienyl)]

[(η5-(1-COCH3-4-methoxy-6-phenylcyclohexadienyl))Mn(CO)3]