3-benzoyl-1-(2,2-di-tert-butyl-7-phenylselanyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-1H-pyrimidine-2,4-dione

Base Information

Chemical Name:3-benzoyl-1-(2,2-di-tert-butyl-7-phenylselanyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-1H-pyrimidine-2,4-dione
CAS No.:677346-93-9
Molecular Formula:C₃₀H₃₆N₂O₆SeSi
Molecular Weight:627.671
Hs Code.:

3-benzoyl-1-(2,2-di-<i>tert</i>-butyl-7-phenylselanyl-tetrahydro-furo[3,2-<i>d</i>][1,3,2]dioxasilin-6-yl)-1<i>H</i>-pyrimidine-2,4-dione

Synonyms:3-benzoyl-1-(2,2-di-tert-butyl-7-phenylselanyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-1H-pyrimidine-2,4-dione

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Chemical Property of 3-benzoyl-1-(2,2-di-tert-butyl-7-phenylselanyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-1H-pyrimidine-2,4-dione

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Technology Process of 3-benzoyl-1-(2,2-di-tert-butyl-7-phenylselanyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-1H-pyrimidine-2,4-dione

There total 1 articles about 3-benzoyl-1-(2,2-di-tert-butyl-7-phenylselanyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-1H-pyrimidine-2,4-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 98-88-4
benzoyl chloride

: 503043-97-8
3',5'-O-(di-tert-butylsilylene)-2'-deoxy-2'-phenylselenouridine

: 677346-93-9
3-benzoyl-1-(2,2-di-tert-butyl-7-phenylselanyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-1H-pyrimidine-2,4-dione

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 2h;
DOI:10.1021/jo030262u

Reference yield: 93.0%

: 677346-93-9
3-benzoyl-1-(2,2-di-tert-butyl-7-phenylselanyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-1H-pyrimidine-2,4-dione

: 677346-94-0
C₃₀H₃₆N₂O₇SeSi

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃; for 2h;
DOI:10.1021/jo030262u

Reference yield:

: 677346-93-9
3-benzoyl-1-(2,2-di-tert-butyl-7-phenylselanyl-tetrahydro-furo[3,2-d][1,3,2]dioxasilin-6-yl)-1H-pyrimidine-2,4-dione

: 677346-77-9
1'-azido-N³-benzoyl-3',5'-O-(di-tert-butylsilylene)uridine

Guidance literature:: Multi-step reaction with 4 steps

1: 93 percent / m-CPBA / CH₂Cl₂ / 2 h / 0 °C

2: 56 percent / Et₃N / tetrahydrofuran / 4 h / 50 °C

3: dimethyldioxirane / CH₂Cl₂; acetone / 0.5 h / -30 °C

4: 44.2 mg / N₃AlEt₂ / CH₂Cl₂; toluene / 4.5 h / -30 °C

With 3,3-dimethyldioxirane; diethylaluminum azide; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; acetone; toluene;
DOI:10.1021/jo030262u