tungsten hexaphenoxide

Base Information

• Chemical Name: tungsten hexaphenoxide
• CAS No.: 799823-45-3
• Molecular Formula: C₃₆H₃₀O₆W
• Molecular Weight: 742.481
• Mol file: 799823-45-3.mol

Synonyms:tungsten hexaphenoxide

Chemical Property of tungsten hexaphenoxide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tungsten hexaphenoxide

There total 7 articles about tungsten hexaphenoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tungsten hexacarbonyl (14040-11-0) + phenol (108-95-2,27073-41-2) → tungsten hexaphenoxide (799823-45-3)

Guidance literature:

In further solvent(s); air-free techniques; refluxed;

DOI:10.1021/om020129c

Reference yield: 88.0%

tungsten(VI) chloride (13283-01-7) + phenol (108-95-2,27073-41-2) → tungsten hexaphenoxide (799823-45-3)

Guidance literature:

In neat (no solvent); byproducts: HCl; absence of air and moisture; excess phenol, refluxing for 3 h, then heating just below refluxing for 4 h; cooling to room temp., EtOH addn., collection (filtration), drying (vac.);

DOI:10.1016/0022-328X(95)05500-O

Reference yield: 48.0%

tris(1,2-ethanediolato)tungsten(VI) (54153-67-2) + Phenyl acetate (122-79-2,34474-31-2) → tungsten hexaphenoxide (799823-45-3)

Guidance literature:

In chlorobenzene; refluxing (6 h); washing (10% aqueous NaOH, water), evapn. (vac.), dissoln. (acetonitrile, slow evapn.;

DOI:10.1016/S0277-5387(98)00281-2

upstream raw materials:

tungsten hexacarbonyl

phenol

tris(1,2-ethanediolato)tungsten(VI)

Phenyl acetate

Downstream raw materials:

tetrakis(2-methylphenyl)tungsten(IV)

Refernces

• 1、 Xu, Li,Whitmire, Kenton H.. "Hybrid metal carbonyl-oxide clusters: Synthesis and structure of [Et4N]2[(OC)5WSbW3(CO)9( μ3-OMe)2(μ3-O)WO2(OR)] (R = Me, H)". . p. 2581 - 2583. Retrieved 2002.
• 2、 Cong, Shan,Tian, Yuyu,Li, Qingwen,Zhao, Zhigang,Geng, Fengxia. "Single-crystalline tungsten oxide quantum dots for fast pseudocapacitor and electrochromic applications". . p. 4260 - 4267. Retrieved 2014.