1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-propan-1-one oxime

Base Information

• Chemical Name: 1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-propan-1-one oxime
• CAS No.: 79727-81-4
• Molecular Formula: C₁₉H₂₇NO₃
• Molecular Weight: 317.428

Synonyms:1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-propan-1-one oxime

Chemical Property of 1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-propan-1-one oxime

Chemical Property:

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Technology Process of 1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-propan-1-one oxime

There total 2 articles about 1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-propan-1-one oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

1-[4-((E)-3,7-Dimethyl-octa-2,6-dienyloxy)-phenyl]-propan-1-one oxime (79727-64-3) → 1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-propan-1-one oxime (79727-81-4)

Guidance literature:

With monoperoxyphthalic acid;

DOI:10.1135/cccc19811614

Reference yield:

4-(3,7-dimethyl-2,6-octadienyloxy)propiophenone (37087-78-8) → 1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-propan-1-one oxime (79727-81-4)

Guidance literature:

Multi-step reaction with 2 steps

1: NaOH, hydroxylamine hydrochloride / ethanol; H₂O / Ambient temperature

2: 50 percent / monoperphthalic acid

With sodium hydroxide; monoperoxyphthalic acid; hydroxylamine hydrochloride; In ethanol; water;

DOI:10.1135/cccc19811614

Reference yield: 57.0%

1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-propan-1-one oxime (79727-81-4) + ethyl bromoacetate (105-36-2) → [1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-prop-(Z)-ylideneaminooxy]-acetic acid ethyl ester (79727-82-5)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; at 15 - 20 ℃;

DOI:10.1135/cccc19811614

upstream raw materials:

1-[4-((E)-3,7-Dimethyl-octa-2,6-dienyloxy)-phenyl]-propan-1-one oxime

4-(3,7-dimethyl-2,6-octadienyloxy)propiophenone

Downstream raw materials:

[1-{4-[(E)-5-(3,3-Dimethyl-oxiranyl)-3-methyl-pent-2-enyloxy]-phenyl}-prop-(Z)-ylideneaminooxy]-acetic acid ethyl ester

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