di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel

Base Information

• Chemical Name: di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel
• CAS No.: 79928-40-8
• Molecular Formula: C₂₀H₃₀Br₂Ni₂
• Molecular Weight: 547.646
• Mol file: 79928-40-8.mol

Synonyms:di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel

Chemical Property of di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel

There total 1 articles about di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

8-bromo-7-methyl-3-methyleneocta-1,6-diene (26903-21-9) + 3-bromo-2-methyl-6-methyleneocta-1,7-diene (79926-08-2) + tetracarbonyl nickel (13463-39-3,71564-36-8) → di-μ-bromo-bis(1-3-η-2-methyl-6-methyleneocta-2,7-dienyl)dinickel (79928-40-8)

Guidance literature:

In benzene; a soln. of the bromide in dry benzene was slowly added to a stirred soln. of Ni(CO)4 in benzene at 40°C over 2 h; after the mixt. had been stirred at 40°C for 2 h; the excess of Ni(CO)4 and the solvent were removed under reduced pressure below 20°C;

DOI:10.1039/P19810002411

upstream raw materials:

8-bromo-7-methyl-3-methyleneocta-1,6-diene

3-bromo-2-methyl-6-methyleneocta-1,7-diene

tetracarbonyl nickel