1-(benzyl)-3-(2,4,6-trimethylphenyl)imidazolium chloride

Base Information

• Chemical Name: 1-(benzyl)-3-(2,4,6-trimethylphenyl)imidazolium chloride
• CAS No.: 1020264-55-4
• Molecular Formula: C₁₉H₂₁N₂*Cl
• Molecular Weight: 312.842
• Mol file: 1020264-55-4.mol

Synonyms:1-(benzyl)-3-(2,4,6-trimethylphenyl)imidazolium chloride

Chemical Property of 1-(benzyl)-3-(2,4,6-trimethylphenyl)imidazolium chloride

Chemical Property:

Purity/Quality:

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Technology Process of 1-(benzyl)-3-(2,4,6-trimethylphenyl)imidazolium chloride

There total 1 articles about 1-(benzyl)-3-(2,4,6-trimethylphenyl)imidazolium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

benzyl chloride (100-44-7) + N-(2,4,6-trimethylphenyl)imidazole (25364-44-7) → 1-(benzyl)-3-(2,4,6-trimethylphenyl)imidazolium chloride (1020264-55-4)

Guidance literature:

In acetonitrile; for 12h; Reflux; Inert atmosphere;

DOI:10.1039/c0dt00932f

Reference yield: 98.0%

Ag(1+)*OC(CF3)3(1-)=Ag(OC(CF3)3) (918824-07-4) + 1-(benzyl)-3-(2,4,6-trimethylphenyl)imidazolium chloride (1020264-55-4) → silver(1-(benzyl)-3-(mesityl)imidazol-2-ylidene) chloride

Guidance literature:

In acetonitrile; under Ar, in absence of light; mixt. of imidazolium salt and AgOC(CF3)3 in MeCN stirred at room temp. for 2 h; soln. filtered through Celite; solvent removed under vac.; repptd. from CH2Cl2-ether;

DOI:10.1039/b900136k

Reference yield: 97.0%

1-(benzyl)-3-(2,4,6-trimethylphenyl)imidazolium chloride (1020264-55-4) + silver(l) oxide (20667-12-3) → silver(1-(benzyl)-3-(mesityl)imidazol-2-ylidene) chloride

Guidance literature:

In dichloromethane; (Ar) Ag2O and imidazolium salt in CH2Cl2 were stirred at room temp. for 4 h; soln. was filtered through Celite, solvent was removed in vacuo, residuewas dissolved in CH2Cl2, pentane was added, ppt. was filtered and dried in vacuo;

DOI:10.1039/c0dt00932f

upstream raw materials:

benzyl chloride

N-(2,4,6-trimethylphenyl)imidazole