TRIPHENYL STANNYL DIMETHYL PHENYL SILANE

Base Information

• Chemical Name: TRIPHENYL STANNYL DIMETHYL PHENYL SILANE
• CAS No.: 210362-76-8
• Molecular Formula: C26H26 Si Sn
• Molecular Weight: 485.28
• Mol file: 210362-76-8.mol

Synonyms:Silane,dimethylphenyl(triphenylstannyl)- (9CI)

Chemical Property of TRIPHENYL STANNYL DIMETHYL PHENYL SILANE

Chemical Property:

• Vapor Pressure: 1.01E-08mmHg at 25°C
• Melting Point: 64 °C
• Boiling Point: 474.7°C at 760 mmHg
• Flash Point: 240.9°C
• PSA: 0.00000
• LogP: 3.85080

Purity/Quality:

97% ^*data from raw suppliers

TRIPHENYL STANNYL DIMETHYL PHENYL SILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIPHENYL STANNYL DIMETHYL PHENYL SILANE

There total 3 articles about TRIPHENYL STANNYL DIMETHYL PHENYL SILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

fluorodimethylphenylsilane (454-57-9) + triphenyltin chloride (639-58-7) → triphenylstannylphenyldimethylsilane (210362-76-8)

Guidance literature:

With magnesium; In tetrahydrofuran; byproducts: MgFCl; Schlenk technique, N2; mixt. (Mg excess) stirring for 72 h, THF vac. removal, residue extn. (Et2O), Et2O layer vac. evapn.; residue recrystn. (Et2O/n-hexane); elem. anal.;

DOI:10.1080/10426509708044214

Reference yield:

bis(triphenylstannyl)dodecamethylhexasilane → triphenylstannylphenyldimethylsilane (210362-76-8)

Guidance literature:

Multi-step reaction with 2 steps

1: SnCl₄ / toluene

2: Mg / tetrahydrofuran

With SnCl₄; Mg; In tetrahydrofuran; toluene;

DOI:10.1515/znb-1999-0217

Reference yield:

sodium triphenylstannide → triphenylstannylphenyldimethylsilane (210362-76-8)

Guidance literature:

Multi-step reaction with 3 steps

1: tetrahydrofuran

2: SnCl₄ / toluene

3: Mg / tetrahydrofuran

With SnCl₄; Mg; In tetrahydrofuran; toluene;

DOI:10.1515/znb-1999-0217

upstream raw materials:

fluorodimethylphenylsilane

triphenyltin chloride

Refernces

• 1、 Hummeltenberg, Reinhard,Jurkschat, Klaus,Uhlig, Frank. "A convenient one-pot synthesis of stannylsilanes". . p. 255 - 261. Retrieved 2007/10/03.