(C₆H₅)SCH₂B(C₆F₅)2

Base Information

• Chemical Name: (C₆H₅)SCH₂B(C₆F₅)2
• CAS No.: 1311031-15-8
• Molecular Formula: C₁₉H₇BF₁₀S
• Molecular Weight: 468.126
• Mol file: 1311031-15-8.mol

Synonyms:(C₆H₅)SCH₂B(C₆F₅)2

Chemical Property of (C₆H₅)SCH₂B(C₆F₅)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₅)SCH₂B(C₆F₅)2

There total 2 articles about (C₆H₅)SCH₂B(C₆F₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

2-bromo-1-(methylsulfanyl)benzene (19614-16-5) + bis(pentafluorophenyl)boron chloride (2720-03-8) → (C6H5)SCH2B(C6F5)2 (1311031-15-8)

Guidance literature:

With n-BuLi; In diethyl ether; (N2); using Schlenk techniques; addn. of BrC6H4SMe to Et2O, stirring fora few minutes in acetone/dry ice bath, addn. of soln. BuLi/hexane at -7 8°C, stirring for 2 h, drying (vac.), mixing with cold soln. ClB(C6F5)2 in pentane, stirring overnight; filtration, extn. of ppt. into toluene, removal of solvent; elem. anal.;

DOI:10.1021/om200336t

Reference yield: 32.0%

methyl-phenyl-thioether (100-68-5) + bis(pentafluorophenyl)boron chloride (2720-03-8) → (C6H5)SCH2B(C6F5)2 (1311031-15-8)

Guidance literature:

With n-BuLi; In diethyl ether; hexane; (N2); using Schlenk techniques; addn. of PhSMe to Et2O, stirring for a few minutes in acetone/dry ice bath, addn. of soln. BuLi/hexane at -78°C, stirring for 2 h, drying (vac.), mixing with cold soln. ClB(C6F5)2 in pentane, stirring overnight; filtration, extn. of ppt. into toluene, removal of solvent; elem. anal.;

DOI:10.1021/om200336t

Reference yield: 92.0%

(hex-1-yn-1-yl)benzene (1129-65-3) + (C6H5)SCH2B(C6F5)2 (1311031-15-8) → C3H2BS(C6H5)2(C4H9)(C6F5)2 (1311031-12-5)

Guidance literature:

In toluene; (N2); using Schlenk techniques; dissolving of PhSCH2B(C6F5)2 in toluene at -38°C, addn. of PhCCC4H9 via syringe, stirring overnight; evapn. of solvent, addn. of cold pentane, freezing overnight, pptn.; elem. anal.;

DOI:10.1021/om200336t

upstream raw materials:

methyl-phenyl-thioether

bis(pentafluorophenyl)boron chloride

2-bromo-1-(methylsulfanyl)benzene

Downstream raw materials:

C₃H₃BS(C₆H₅)(C₄H₉)(C₆F₅)2

C₃H₂BS(C₆H₅)(C₂H₅)2(C₆F₅)2

C₆H₅SCH₂B(C₆F₅)2OP(C₂H₅)3

C₃H₃BS(C₆H₅)2(C₆F₅)2