bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II)

Base Information

• Chemical Name: bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II)
• CAS No.: 114550-41-3
• Molecular Formula: C₅₂H₄₂N₆Ru
• Molecular Weight: 852.016
• Mol file: 114550-41-3.mol

Synonyms:bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II)

Chemical Property of bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II)

There total 1 articles about bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(m-chlorobenzoato)(μ-oxo)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(IV) (92694-66-1) + zinc (7440-66-6) → bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II) (114550-41-3)

Guidance literature:

In acetonitrile; benzene; stirring {RuTTP(mCB)}2O and Zn in 1 : 1 CH3CN/benzene (room temp., 2 h); isolation under vacuum, eluting with benzene down a neutral alumina column, removal of solvent under vacuum;

DOI:10.1021/ja00221a021

Reference yield:

bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II) (114550-41-3) → bis(tetrahydrofuran)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II) (97877-73-1)

Guidance literature:

With tetrahydrofuran; In tetrahydrofuran; dissolving in THF, stirring for 48h; chromy. (neutral alumina/THF), vacuum;

DOI:10.1021/ja00221a021

Reference yield:

bis(acetonitrile)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II) (114550-41-3) → bis((5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(II))

Guidance literature:

In neat (no solvent); heating (190°C, vacuum) according to Collman, J. P., Barnes, C. E., Swegston, P. N., Ibers, J. A. J. Am. Chem. Soc. {1984} 106, 3500;

DOI:10.1021/ja00221a021

upstream raw materials:

bis(m-chlorobenzoato)(μ-oxo)(5,10,15,20-tetra-p-tolylporphyrinato)ruthenium(IV)

zinc

Downstream raw materials:

bis(tetrahydrofuran)(5,10,15,20-tetramesitylporphyrinato)ruthenium(II)

Ru(meso-tetrakis(4-methylphenyl)porphyrin)(EtSH)2

Ru(meso-tetrakis(4-methylphenyl)porphyrin)(MeSMe)2

Ru(meso-tetrakis(4-methylphenyl)porphyrin)(EtSSEt)2