zinc 5,15-di(4-hydroxyphenyl)porphyrin

Base Information

• Chemical Name: zinc 5,15-di(4-hydroxyphenyl)porphyrin
• CAS No.: 173428-06-3
• Molecular Formula: C₃₂H₂₀N₄O₂Zn
• Molecular Weight: 557.926
• Mol file: 173428-06-3.mol

Synonyms:zinc 5,15-di(4-hydroxyphenyl)porphyrin

Chemical Property of zinc 5,15-di(4-hydroxyphenyl)porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zinc 5,15-di(4-hydroxyphenyl)porphyrin

There total 1 articles about zinc 5,15-di(4-hydroxyphenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

di(pyrrol-2-yl)methane (21211-65-4) + zinc(II) acetate dihydrate (5970-45-6) + 4-(hydroxylmethyl)benzaldehyde (52010-97-6) → zinc 5,15-di(4-hydroxyphenyl)porphyrin (173428-06-3)

Guidance literature:

With BF₃*OEt₂; p-chloranil; In methanol; acetic acid; (N2); reaction of the dipyrrole, the aldehyde and BF3*OEt2 in AcOH/MeOH 20 h at room temp., reaction with p-chloranil and the Zn salt, reflux 1 h;

DOI:10.1039/CC9960002505

Reference yield: 61.0%

zinc 5,15-di(4-hydroxyphenyl)porphyrin (173428-06-3) + 4-(3,4-di(dodecyloxy)benzoyloxy)benzoic acid → Zn(C20H10N4((C6H4OCO)2C6H3(O(CH2)11CH3)2)2) (187584-89-0)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In not given; flash chromy., crystn.; elem. anal.;

Reference yield: 58.0%

zinc 5,15-di(4-hydroxyphenyl)porphyrin (173428-06-3) + C46H85NO5 → C124H186N6O10Zn

Guidance literature:

With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; toluene; at 65 ℃; for 12h;

DOI:10.1002/anie.201407302

upstream raw materials:

di(pyrrol-2-yl)methane

zinc(II) acetate dihydrate

4-(hydroxylmethyl)benzaldehyde

Downstream raw materials:

[Zn(C₃₂H₁₈N₄O₂(COC₆H₃(OC₈H₁₇)2)2)]

[Zn(C₃₂H₁₈N₄O₂(COC₆H₂(OC₈H₁₇)3)2)]

[Zn(C₃₂H₁₈N₄O₂(COC₆H₃(OC₁₄H₂₉)2)2)]

Zn(C₂₀H₁₀N₄((C₆H₄OCO)2C₆H₃(O(CH₂)11CH₃)2)2)