1-(6-Bromohexyloxy)-4-methoxybenzene

Base Information

• Chemical Name: 1-(6-Bromohexyloxy)-4-methoxybenzene
• CAS No.: 20744-11-0
• Molecular Formula: C13H19 Br O2
• Molecular Weight: 287.197
• Hs Code.: 2909309090
• DSSTox Substance ID: DTXSID60366311
• Wikidata: Q82151456
• Mol file: 20744-11-0.mol

Synonyms:20744-11-0;1-(6-BROMOHEXYLOXY)-4-METHOXYBENZENE;1-[(6-BROMOHEXYL)OXY]-4-METHOXYBENZENE;Benzene, 1-[(6-bromohexyl)oxy]-4-methoxy-;1-[6-bromohexyloxy]-4-methoxybenzene;1-(6-bromohexoxy)-4-methoxybenzene;SCHEMBL9689470;DTXSID60366311;YGHAMCWRCXLFCH-UHFFFAOYSA-N;6-(4-methoxyphenoxy)hexyl bromide;A1-26302

Chemical Property of 1-(6-Bromohexyloxy)-4-methoxybenzene

Chemical Property:

• Vapor Pressure: 3.6E-05mmHg at 25°C
• Refractive Index: 1.516
• Boiling Point: 364.1°C at 760 mmHg
• Flash Point: 152.1°C
• PSA: 18.46000
• Density: 1.231g/cm³
• LogP: 4.02930
• XLogP3: 4.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 8
• Exact Mass: 286.05684
• Heavy Atom Count: 16
• Complexity: 156

Purity/Quality:

99% ^*data from raw suppliers

1-(6-BROMOHEXYLOXY)-4-METHOXYBENZENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)OCCCCCCBr

Technology Process of 1-(6-Bromohexyloxy)-4-methoxybenzene

There total 3 articles about 1-(6-Bromohexyloxy)-4-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1 ,6-dibromohexane (629-03-8) + 4-methoxy-phenol (150-76-5) → 6-(4-methoxyphenoxy)hexyl bromide (20744-11-0)

Guidance literature:

With potassium carbonate; potassium iodide; In acetone; at 65 ℃;

DOI:10.1039/d0nj02362k

Reference yield: 91.0%

1-bromo-6-hexanol (4286-55-9) + 4-methoxy-phenol (150-76-5) → 6-(4-methoxyphenoxy)hexyl bromide (20744-11-0)

Guidance literature:

With di-isopropyl azodicarboxylate; triphenylphosphine; In tetrahydrofuran; at 20 ℃; for 18h; Inert atmosphere;

DOI:10.1002/anie.201504524

Reference yield:

→ 6-(4-methoxyphenoxy)hexyl bromide (20744-11-0)

Guidance literature:

p-Methoxyphenol, Dibromhexan;

upstream raw materials:

1 ,6-dibromohexane

4-methoxy-phenol

1-bromo-6-hexanol

Downstream raw materials:

1-(6-iodohexyloxy)-4-methoxybenzene

1,22-bis-(4-methoxy-phenoxy)-docosane