N-(1-ethylpropyl)-N'-(4-amino-2,5-di-tert-butylphenyl)perylene-3,4:9,10-tetracarboxylic diimide

Base Information

• Chemical Name: N-(1-ethylpropyl)-N'-(4-amino-2,5-di-tert-butylphenyl)perylene-3,4:9,10-tetracarboxylic diimide
• CAS No.: 522647-63-8
• Molecular Formula: C₄₃H₄₁N₃O₄
• Molecular Weight: 663.816
• Mol file: 522647-63-8.mol

Synonyms:N-(1-ethylpropyl)-N'-(4-amino-2,5-di-tert-butylphenyl)perylene-3,4:9,10-tetracarboxylic diimide

Chemical Property of N-(1-ethylpropyl)-N'-(4-amino-2,5-di-tert-butylphenyl)perylene-3,4:9,10-tetracarboxylic diimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N-(1-ethylpropyl)-N'-(4-amino-2,5-di-tert-butylphenyl)perylene-3,4:9,10-tetracarboxylic diimide

There total 2 articles about N-(1-ethylpropyl)-N'-(4-amino-2,5-di-tert-butylphenyl)perylene-3,4:9,10-tetracarboxylic diimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

2,5-di-tert-butylbenzene-1,4-diamine (22162-01-2) + 9-(1-ethylpropyl)-1H-2-benzopyrano[6',5',4':10,5,6]anthra[2,1,9-def]isoquinoline-1,3,8,10(9H)-tetraone (522647-62-7) → N-(1-ethylpropyl)-N'-(4-amino-2,5-di-tert-butylphenyl)perylene-3,4:9,10-tetracarboxylic diimide (522647-63-8)

Guidance literature:

With 1H-imidazole; zinc diacetate; at 160 ℃; for 3.5h;

DOI:10.1039/b208824j

Reference yield:

N,N'-bis(1-ethylpropyl)-3,4:9,10-perylenebis(dicarboximide) (110590-81-3) → N-(1-ethylpropyl)-N'-(4-amino-2,5-di-tert-butylphenyl)perylene-3,4:9,10-tetracarboxylic diimide (522647-63-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 20 percent / KOH / 2-methyl-propan-2-ol / 0.5 h / 100 °C

2: 67 percent / Zn(OAc)2; imidazole / 3.5 h / 160 °C

With 1H-imidazole; potassium hydroxide; zinc diacetate; In tert-butyl alcohol;

DOI:10.1039/b208824j

Reference yield: 54.0%

N-[6-(heptan-3-yl)-1,4-dihydro-4-oxopyrimidin-2-yl]-1H-imidazole-1-carboxamide (522647-64-9) + N-(1-ethylpropyl)-N'-(4-amino-2,5-di-tert-butylphenyl)perylene-3,4:9,10-tetracarboxylic diimide (522647-63-8) → N-(1-ethylpropyl)-N'-{4-[2-ureido-6-(1-ethylpentyl)-4[1H]-pyrimidinone]-2',5'-di-tert-butylphenyl}perylene-3,4:9,10-tetracarboxylic diimide

Guidance literature:

In chloroform; for 18h; Heating;

DOI:10.1039/b208824j

upstream raw materials:

2,5-di-tert-butylbenzene-1,4-diamine

9-(1-ethylpropyl)-1H-2-benzopyrano[6',5',4':10,5,6]anthra[2,1,9-def]isoquinoline-1,3,8,10(9H)-tetraone

N,N'-bis(1-ethylpropyl)-3,4:9,10-perylenebis(dicarboximide)