3-methoxycarbonylphenylzinc iodide

Base Information

• Chemical Name: 3-methoxycarbonylphenylzinc iodide
• CAS No.: 148651-38-1
• Molecular Formula: C₈H₇IO₂Zn
• Molecular Weight: 327.437
• Mol file: 148651-38-1.mol

Synonyms:3-methoxycarbonylphenylzinc iodide

Chemical Property of 3-methoxycarbonylphenylzinc iodide

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 3-methoxycarbonylphenylzinc iodide

There total 1 articles about 3-methoxycarbonylphenylzinc iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

methyl 3-iodo-benzoate (618-91-7) + zinc (7440-66-6) → 3-methoxycarbonylphenylzinc iodide (148651-38-1)

Guidance literature:

With water; In further solvent(s); byproducts: C6H5C(O)CH3; Sonication; (N2); solvent = 1,1,3,3-tetramethylurea contg. water; 2 equivs. of Zn powder used; 50 °C; ultrasound applied for 20 h; 100% conversion; not isolated; conversion and yield detd. by quenching with I2;

DOI:10.1246/cl.1993.469

Reference yield: 90.0%

1-Iodoheptane (4282-40-0) + 3-methoxycarbonylphenylzinc iodide (148651-38-1) → methyl 3-heptylbenzoate (1220102-00-0)

Guidance literature:

With chloro(1,5-cyclooctadiene)rhodium(I) dimer; 3-diphenylphosphino-2-(diphenylphosphino)methyl-2-methylpropyl acetate; In tetramethylurea; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1021/ol100210u

Reference yield: 82.0%

4-cyanobenzaldehyde (105-07-7) + 3-methoxycarbonylphenylzinc iodide (148651-38-1) → methyl 3-[(4-cyanophenyl)hydroxymethyl]benzoate

Guidance literature:

With chromium chloride; chloro-trimethyl-silane; In various solvent(s); Ambient temperature;

DOI:10.1246/cl.1996.1069

upstream raw materials:

methyl 3-iodo-benzoate

zinc

Downstream raw materials:

1-methoxycarbonyl-3-methylbenzene

biphenyl-3,3'-dicarboxylic acid dimethyl ester

diethyl 2-[3-(methoxycarbonyl)phenyl]ethylphosphonate

methyl 3-heptylbenzoate