7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

Base Information

Chemical Name:7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol
CAS No.:233255-50-0
Molecular Formula:C₄₁H₅₂O₆Si
Molecular Weight:668.946
Hs Code.:

Synonyms:7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

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Chemical Property of 7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

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Technology Process of 7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

There total 1 articles about 7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 233255-49-7
7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

: 74-88-4
methyl iodide

: 233255-50-0
7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

Guidance literature:: With sodium hydride; In tetrahydrofuran;
DOI:10.1016/S0040-4039(99)00769-8

Reference yield: 93.0%

: 233255-50-0
7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

: 233255-51-1
7,8-dideoxy-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran;
DOI:10.1016/S0040-4039(99)00769-8

Reference yield:

: 233255-50-0
7,8-dideoxy-1-O-[(1,1-dimethylethyl)diphenylsilyl]-2,4,5-tri-O-methyl-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

: 1,7,8-trideoxy-2,4,5-tri-O-methyl-1-[oxido(phenylmethyl)imino]-3,6-bis-O-(phenylmethyl)-D-glycero-D-manno-oct-7-enitol

Guidance literature:: Multi-step reaction with 3 steps

1: 93 percent / TBAF / tetrahydrofuran / 24 h / 20 °C

2: 85 percent / PCC; AcONa; molecular sieves / CH₂Cl₂ / 4 h / 20 °C

3: 74 percent / pyridine / CH₂Cl₂ / 12 h / Heating

With pyridine; molecular sieve; tetrabutyl ammonium fluoride; sodium acetate; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane;
DOI:10.1081/CAR-120004333