(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

Base Information

Chemical Name:(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate
CAS No.:361525-09-9
Molecular Formula:C₆₅H₉₂O₁₂
Molecular Weight:1065.44
Hs Code.:

(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

Synonyms:(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

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Chemical Property of (1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

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Technology Process of (1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

There total 11 articles about (1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: (1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-(tert-butyldimethylsiloxy)butyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-(triphenylsiloxy)-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

: 361525-09-9
(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; at 20 ℃; for 48h;
DOI:10.1039/b305818b

Reference yield: 84.0%

: 443304-98-1
11-(4-methoxy-benzyloxy)-2,4,6,8,10,12-hexamethyl-5-triisopropylsilanyloxy-docosa-2,6,8-trienoic acid 4-(tert-butyl-dimethyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl ester

: 361525-09-9
(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

Guidance literature:: With hydrogenchloride; In tetrahydrofuran;
DOI:10.1055/s-2002-22726

Reference yield:

: 331626-81-4
(2R,3R,4R)-5-(tert-Butyl-dimethyl-silanyloxy)-1,3,4-tris-(4-methoxy-benzyloxy)-pentan-2-ol

: 361525-09-9
(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-hydroxy-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: 79 percent / DCC; DMAP; DMAP*HCl

2.1: 9-BBN / tetrahydrofuran / 12 h / 20 °C

2.2: 84 percent / aq. K₃PO₄ / PdCl₂(dppf) / tetrahydrofuran / 0.5 h / 70 °C

3.1: 84 percent / aq. HCl / tetrahydrofuran

With hydrogenchloride; dmap; 9-borabicyclo[3.3.1]nonane dimer; 4-(dimethylamino)pyridine hydrochloride; dicyclohexyl-carbodiimide; In tetrahydrofuran; 2.2: Suzuki reaction;
DOI:10.1055/s-2002-22726