1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene

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Chemical Name:1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene
CAS No.:361525-06-6
Molecular Formula:C₂₆H₄₂O₂
Molecular Weight:386.618
Hs Code.:

Synonyms:1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene

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Chemical Property of 1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene

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Technology Process of 1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene

There total 2 articles about 1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 361525-05-5
1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene

: 74-88-4
methyl iodide

: 361525-06-6
1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene

Guidance literature:: 1-[(1R,2S)-1-((S)-3,3-Dibromo-1-methyl-allyl)-2-methyl-dodecyloxymethyl]-4-methoxy-benzene; With n-butyllithium; In tetrahydrofuran;

methyl iodide; at -78 ℃; Further stages.;
DOI:10.1021/jo0158128

Reference yield:

: 331625-96-8
(2R,3R,4S)-3-(4-Methoxy-benzyloxy)-2,4-dimethyl-tetradecanal

: 361525-06-6
1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 95 percent / PPh₃ / CH₂Cl₂ / 20 °C

2.1: BuLi / tetrahydrofuran

2.2: 93 percent / -78 °C

With n-butyllithium; triphenylphosphine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo0158128

Reference yield: 88.0%

: 361525-06-6
1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene

: 361525-03-3
(2E,6E)-(4R,5R)-7-Iodo-2,4,6-trimethyl-5-triphenylsilanyloxy-hepta-2,6-dienoic acid ethyl ester

: 637740-64-8
ethyl (2E,4R,5R,6E,8E,10S,11R,12S)-2,4,6,8,10,12-hexamethyl-5-(triphenylsiloxy)-11-(4-methoxybenzyloxy)-2,6,8-docosatrienoate

Guidance literature:: 1-Methoxy-4-[(1R,2S)-2-methyl-1-((S)-1-methyl-but-2-ynyl)-dodecyloxymethyl]-benzene; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 20 ℃; for 12h;

(2E,6E)-(4R,5R)-7-Iodo-2,4,6-trimethyl-5-triphenylsilanyloxy-hepta-2,6-dienoic acid ethyl ester; With potassium phosphate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In tetrahydrofuran; water; N,N-dimethyl-formamide; at 65 ℃; for 0.5h; Further stages.;
DOI:10.1039/b305818b