5,5-bis(benzenesulfonyl)-1-[(5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-2-oxo-3-(phenylselanyl)oxolan-3-yl]pentyl acetate

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Chemical Name:5,5-bis(benzenesulfonyl)-1-[(5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-2-oxo-3-(phenylselanyl)oxolan-3-yl]pentyl acetate
CAS No.:1432519-10-2
Molecular Formula:C₃₉H₄₈O₅S₂Se
Molecular Weight:739.899
Hs Code.:

Synonyms:5,5-bis(benzenesulfonyl)-1-[(5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-2-oxo-3-(phenylselanyl)oxolan-3-yl]pentyl acetate

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Chemical Property of 5,5-bis(benzenesulfonyl)-1-[(5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-2-oxo-3-(phenylselanyl)oxolan-3-yl]pentyl acetate

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Technology Process of 5,5-bis(benzenesulfonyl)-1-[(5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-2-oxo-3-(phenylselanyl)oxolan-3-yl]pentyl acetate

There total 3 articles about 5,5-bis(benzenesulfonyl)-1-[(5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-2-oxo-3-(phenylselanyl)oxolan-3-yl]pentyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1432519-07-7
(5R)-3-[1-hydroxy-5,5-bis(phenylsulfanyl)pentyl]-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-3-(phenylselanyl)-oxolan-2-one

: 1432519-10-2
5,5-bis(benzenesulfonyl)-1-[(5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-2-oxo-3-(phenylselanyl)oxolan-3-yl]pentyl acetate

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 ℃; for 3h; Cooling with ice;
DOI:10.1039/c3ob40115d

Reference yield:

: 906520-19-2
5,5-bis(phenylthio)pentanal

: 1432519-10-2
5,5-bis(benzenesulfonyl)-1-[(5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-2-oxo-3-(phenylselanyl)oxolan-3-yl]pentyl acetate

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium diisopropyl amide / hexane; tetrahydrofuran / 0.75 h / -78 °C

1.2: 0.08 h

1.3: -78 °C

2.1: dmap; triethylamine / dichloromethane / 3 h / 0 °C / Cooling with ice

With dmap; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/c3ob40115d

Reference yield:

: 1365840-73-8
(3S,5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]-oxy}-3-(phenylselanyl)oxolan-2-one

: 1432519-10-2
5,5-bis(benzenesulfonyl)-1-[(5R)-5-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl]oxy}-2-oxo-3-(phenylselanyl)oxolan-3-yl]pentyl acetate

Guidance literature:: Multi-step reaction with 2 steps

1.1: lithium diisopropyl amide / hexane; tetrahydrofuran / 0.75 h / -78 °C

1.2: 0.08 h

1.3: -78 °C

2.1: dmap; triethylamine / dichloromethane / 3 h / 0 °C / Cooling with ice

With dmap; triethylamine; lithium diisopropyl amide; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/c3ob40115d