(1,3-bis(diphenylphosphino)propane)Pt(CO₃)

Base Information

Chemical Name:(1,3-bis(diphenylphosphino)propane)Pt(CO₃)
CAS No.:156053-80-4
Molecular Formula:C₂₈H₂₆O₃P₂Pt
Molecular Weight:667.54
Hs Code.:

(1,3-bis(diphenylphosphino)propane)Pt(CO<sub>3</sub>)

Synonyms:(1,3-bis(diphenylphosphino)propane)Pt(CO₃)

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Chemical Property of (1,3-bis(diphenylphosphino)propane)Pt(CO₃)

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Technology Process of (1,3-bis(diphenylphosphino)propane)Pt(CO₃)

There total 5 articles about (1,3-bis(diphenylphosphino)propane)Pt(CO₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 59329-00-9
[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

: silver carbonate

: 156053-80-4
(1,3-bis(diphenylphosphino)propane)Pt(CO₃)

Guidance literature:: With water; equimolar amts., stirring in wet CH2Cl2 for 3 h with protection from light; filtration, concn., pptn. on hexane addn., collection (filtration), drying (vac.);
DOI:10.1021/ic9603159

Reference yield: 85.0%

: 59329-00-9
[1,3-bis(diphenylphosphino)propane]dichloroplatinum(II)

: 124-38-9,18923-20-1
carbon dioxide

: 156053-80-4
(1,3-bis(diphenylphosphino)propane)Pt(CO₃)

Guidance literature:: With water; NaO-i-Pr; In tetrahydrofuran; byproducts: NaCl; Ar-atmosphere; slow addn. of propoxide to Pt-complex, standing for 3 h, addn. of 5 equiv. water, bubbling CO2, standing under CO2 overnight; collection, washing, drying;
DOI:10.1021/ic9603159

Reference yield:

: 156053-79-1
[(C₆H₅)2PCH₂CH₂CH₂P(C₆H₅)2]Pt[OCH(CH₃)2]2

: 156053-80-4
(1,3-bis(diphenylphosphino)propane)Pt(CO₃)

Guidance literature:: With CO₂; In tetrahydrofuran; water; under Ar; to soln. Pt-complex/THF (prepared in situ from (dppp)PtCl2 and NaOCH(CH3)2) with added NaCl (to facilitate crystn.) was added water (5 equiv/Pt), soln. stirred, CO2 bubbled through, copious white ppt. within 1 min, stirred 30 min under CO2; centrifuged, washed in air (ether), dried (vac.), dissolved in CH2Cl2, hexane diffused in over 2 d, white powder washed (CH2Cl2/hexane (1:1)), dried (vac.), treatment of mother liquor with hexane gave additional product, elem. anal.;
DOI:10.1021/ja00092a025