N,N,N′,N′,N″,N″-mesitylenetriamine hexaacetic acid

Base Information

• Chemical Name: N,N,N′,N′,N″,N″-mesitylenetriamine hexaacetic acid
• CAS No.: 352689-17-9
• Molecular Formula: C₂₁H₂₇N₃O₁₂
• Molecular Weight: 513.458
• Mol file: 352689-17-9.mol

Synonyms:N,N,N′,N′,N″,N″-mesitylenetriamine hexaacetic acid

Chemical Property of N,N,N′,N′,N″,N″-mesitylenetriamine hexaacetic acid

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of N,N,N′,N′,N″,N″-mesitylenetriamine hexaacetic acid

There total 2 articles about N,N,N′,N′,N″,N″-mesitylenetriamine hexaacetic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

({3,5-bis-[(bis-ethoxycarbonylmethyl-amino)-methyl]-benzyl}-ethoxycarbonylmethyl-amino)-acetic acid ethyl ester → N,N,N′,N′,N″,N″-mesitylenetriamine hexaacetic acid (352689-17-9)

Guidance literature:

With lithium hydroxide; In tetrahydrofuran; methanol; at 25 ℃; for 12h;

DOI:10.1021/ja003193z

Reference yield:

1,3,5-Tris(bromomethyl)benzene (18226-42-1) → N,N,N′,N′,N″,N″-mesitylenetriamine hexaacetic acid (352689-17-9)

Guidance literature:

Multi-step reaction with 2 steps

1: 91 percent / K₂CO₃ / acetonitrile / 12 h / 20 °C / sonication

2: 92 percent / LiOH*H₂O / methanol; tetrahydrofuran / 12 h / 25 °C

With lithium hydroxide; potassium carbonate; In tetrahydrofuran; methanol; acetonitrile;

DOI:10.1021/ja003193z

Reference yield: 85.0%

copper(II) choride dihydrate + N,N,N′,N′,N″,N″-mesitylenetriamine hexaacetic acid (352689-17-9) → 3Cu(2+)*C6H3(CH2N(CH2CO2)2)3(6-)*3H2O=Cu3C6H3(CH2N(CH2CO2)2)3*3H2O

Guidance literature:

In methanol; water; Cu salt in MeOH added to aq. soln. of the acid; stirred for 4 h at room temp.; solid filtered off and washed with MeOH; elem. anal.;

DOI:10.1021/ja003193z

upstream raw materials:

1,3,5-Tris(bromomethyl)benzene