(E)-1-tert-butyl(diphenyl)silylhex-1-ene

Base Information

• Chemical Name: (E)-1-tert-butyl(diphenyl)silylhex-1-ene
• CAS No.: 167865-50-1
• Molecular Formula: C₂₂H₃₀Si
• Molecular Weight: 322.566
• Mol file: 167865-50-1.mol

Synonyms:(E)-1-tert-butyl(diphenyl)silylhex-1-ene

Chemical Property of (E)-1-tert-butyl(diphenyl)silylhex-1-ene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-1-tert-butyl(diphenyl)silylhex-1-ene

There total 4 articles about (E)-1-tert-butyl(diphenyl)silylhex-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

hex-1-yne (693-02-7) + tert-butylchlorodiphenylsilane (58479-61-1) → (E)-1-tert-butyl(diphenyl)silylhex-1-ene (167865-50-1) + 2-tert-butyl(diphenyl)silylhex-1-ene

Guidance literature:

tert-butylchlorodiphenylsilane; With lithium; In tetrahydrofuran; at 0 ℃; for 4h;

With n-butyllithium; at 0 ℃; for 0.75h;

hex-1-yne; In tetrahydrofuran; at -78 ℃; for 1h;

DOI:10.1055/s-2000-6409

Reference yield:

phenyldimethylsilyl chloride (768-33-2) + hex-1-yne (693-02-7) → (E)-1-tert-butyl(diphenyl)silylhex-1-ene (167865-50-1) + 2-tert-butyl(diphenyl)silylhex-1-ene

Guidance literature:

phenyldimethylsilyl chloride; With lithium; In tetrahydrofuran; at 0 ℃;

With zinc(II) chloride; In tetrahydrofuran; diethyl ether; at 0 ℃;

hex-1-yne; With copper(l) iodide; In tetrahydrofuran; diethyl ether; at 0 ℃; Further stages. Title compound not separated from byproducts.;

DOI:10.1039/b513528a

Reference yield:

hex-1-yne (693-02-7) + tert-butylchlorodiphenylsilane (58479-61-1) → (E)-1-tert-butyl(diphenyl)silylhex-1-ene (167865-50-1)

Guidance literature:

With lithium; ammonium chloride; Yield given. Multistep reaction;

upstream raw materials:

chloro-trimethyl-silane

hex-1-yne

tert-butylchlorodiphenylsilane

phenyldimethylsilyl chloride

Downstream raw materials:

(3E)-oct-3-en-2-one

2-tert-butyl(diphenyl)silylhexanal