bis(o-dicarbollyl)nickel(IV)

Base Information

Chemical Name:bis(o-dicarbollyl)nickel(IV)
CAS No.:36548-55-7
Molecular Formula:C₄H₂₂B₁₈Ni
Molecular Weight:323.507
Hs Code.:

Synonyms:bis(o-dicarbollyl)nickel(IV)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(o-dicarbollyl)nickel(IV)

Chemical Property:

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Technology Process of bis(o-dicarbollyl)nickel(IV)

There total 1 articles about bis(o-dicarbollyl)nickel(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: caesium [3,3'-commo-bis(η5-nonahydro-1,2-dicarba-3-nickel-closo-decarborate)]

: 2751-90-8
tetraphenylphosphonium bromide

: 36548-55-7
bis(o-dicarbollyl)nickel(IV)

: tetraphenylphosphonium [3,3'-commo-bis[η5-1,2-dicarba-(3)-nickel(III)-closo-dodecaborate]]

Guidance literature:: With Na₂SO₃; In water; byproducts: CsBr; stoich., Ph4PBr dissolved in H2O at 70°C, Ni complex dissolved inH2O at 70°C, acetate buffer added (pH=4.56), treated with Na2SO3 , filtered, poured into stirred soln. of Ph4PBr at 70°C, pptd.; coagulated (CaCl2), cooled, filtered, washed (H2O), dried (air, vac.) atroom temp., elem. anal.;
DOI:10.1134/S1070328408090078

Reference yield: 89.4%

: 36548-55-7
bis(o-dicarbollyl)nickel(IV)

: 1779-49-3
Methyltriphenylphosphonium bromide

: 12570-01-3
P(C₆H₅)3CH₃{(1.2-C₂B₉H₁₁)2Ni*Br}

Guidance literature:: In dichloromethane; react. in warm CH2Cl2, slow addn. of hexane;; pptn.;;
DOI:10.1021/ja00708a009

Reference yield: 41.9%

: 36548-55-7
bis(o-dicarbollyl)nickel(IV)

: 603-35-0
triphenylphosphine

: 61817-74-1
3,3'-bis(triphenylphosphino)-1,2-dicarba-3-nickela-closo-dodecaborane(II)

Guidance literature:: In ethanol; the mixt. in anhydrous ethanol was refluxed for 2 h, slowly cooled to20°C; ppt. was sepd. by decantation, washed with ethanol and hexane, dried in vac.; elem. anal.;
DOI:10.1023/A:1015098628735