(3S,6S)-3-<3-propyl>-6-<3-propyl>-2,5-piperazinedione

Base Information

Chemical Name:(3S,6S)-3-<3-propyl>-6-<3-propyl>-2,5-piperazinedione
CAS No.:131618-17-2
Molecular Formula:C₃₁H₃₇Cl₃N₄O₈
Molecular Weight:700.016
Hs Code.:

(3S,6S)-3-<3-<N-(allyloxycarbonyl)-N-(benzyloxy)-amino>propyl>-6-<3-<N-(2,2,2-trichloroethoxycarbonyl)-N-(benzyloxy)amino>propyl>-2,5-piperazinedione

Synonyms:(3S,6S)-3-<3-propyl>-6-<3-propyl>-2,5-piperazinedione

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Chemical Property of (3S,6S)-3-<3-propyl>-6-<3-propyl>-2,5-piperazinedione

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Technology Process of (3S,6S)-3-<3-propyl>-6-<3-propyl>-2,5-piperazinedione

There total 11 articles about (3S,6S)-3-<3-propyl>-6-<3-propyl>-2,5-piperazinedione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 131618-16-1
N²-5-(benzyloxy)-N⁵-(allyloxycarbonyl)-L-ornithinyl>-N⁵-(benzyloxy)-N⁵-(2,2,2-trichloroethoxycarbonyl)-L-ornithine 1-methyl ester

: 131618-17-2
(3S,6S)-3-<3-propyl>-6-<3-propyl>-2,5-piperazinedione

Guidance literature:: With 1H-imidazole; In methanol; for 96h; Ambient temperature;
DOI:10.1021/jo00002a005

Reference yield:

: 124620-52-6
N²-(benzyloxycarbonyl)-N⁵-(benzyloxy)-N⁵-<(2,2,2-trichloroethoxy)carbonyl>-L-ornithine 1-tert-butyl ester

: 131618-17-2
(3S,6S)-3-<3-propyl>-6-<3-propyl>-2,5-piperazinedione

Guidance literature:: Multi-step reaction with 6 steps

1: CF₃COOH / CH₂Cl₂

2: diethyl ether

3: 30percent HBr-HOAc / CH₂Cl₂ / 0.17 h

4: Et₃N, EEDQ / CH₂Cl₂

5: 44 percent / 30percent HBr-HOAc / CH₂Cl₂ / 0.17 h

6: 77 percent / imidazole / methanol / 96 h / Ambient temperature

With 1H-imidazole; hydrogen bromide; acetic acid; N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline; triethylamine; trifluoroacetic acid; In methanol; diethyl ether; dichloromethane;
DOI:10.1021/jo00002a005

Reference yield:

: 622-33-3
N-benzyloxyamine

: 131618-17-2
(3S,6S)-3-<3-propyl>-6-<3-propyl>-2,5-piperazinedione

Guidance literature:: Multi-step reaction with 6 steps

1: 96 percent / pyridine / CH₂Cl₂ / 1 h

2: triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran / 13 h / Ambient temperature

3: CF₃COOH / CH₂Cl₂ / 1 h

4: Et₃N, EEDQ / CH₂Cl₂

5: 44 percent / 30percent HBr-HOAc / CH₂Cl₂ / 0.17 h

6: 77 percent / imidazole / methanol / 96 h / Ambient temperature

With pyridine; 1H-imidazole; hydrogen bromide; acetic acid; N-ethoxycarbonyl-2-ethoxy-1,2-dihydroquinoline; triethylamine; triphenylphosphine; trifluoroacetic acid; diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/jo00002a005