RHODIUM(II) ACETATE DIMER DIHYDRATE

Base Information

• Chemical Name: RHODIUM(II) ACETATE DIMER DIHYDRATE
• CAS No.: 29998-99-0
• Molecular Formula: C8H16 O10 Rh2
• Molecular Weight: 478.02
• Hs Code.: 28439090
• Mol file: 29998-99-0.mol

Synonyms:Rhodium,tetrakis(acetato)diaquodi- (7CI); Rhodium, tetrakis(m-acetato)diaquadi-, (Rh-Rh) (8CI); Rhodium, tetrakis[m-(acetato-O:O')]diaquadi-,(Rh-Rh); Tetra-m-acetatodiaquadirhodium;Tetraacetatodiaquadirhodium; Tetrakis(acetato)diaquadirhodium;Tetrakis(acetato)dirhodium dihydrate; Tetrakis(m-acetato)diaquadirhodium

Chemical Property of RHODIUM(II) ACETATE DIMER DIHYDRATE

Chemical Property:

Purity/Quality:

98%min ^*data from raw suppliers

RHODIUM(II) ACETATE DIMER DIHYDRATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R36/38:Irritating to eyes and skin.
• Hazard Codes: Xi:Irritant
• Statements: R36/38:Irritating to eyes and skin.
• Safety Statements: S15:Keep away from heat.; S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advic

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of RHODIUM(II) ACETATE DIMER DIHYDRATE

There total 14 articles about RHODIUM(II) ACETATE DIMER DIHYDRATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

dirhodium tetraacetate + barium perchlorate trihydrate → dirhodium tetracetate dihydrate (917499-87-7,29998-99-0) + [Rh2(CH3CO2)2(H2O)6](2+)*2ClO4(1-)=[Rh2(CH3CO2)2(H2O)6](ClO4)2 + [Rh2(CH3CO2)3(H2O)4](1+)*ClO4(1-)=[Rh2(CH3CO2)3(H2O)4]ClO4 (106564-52-7)

Guidance literature:

With H₂SO₄; In sulfuric acid; byproducts: BaSO4, KClO4; aq. H2SO4; react. of (Rh2(CH3CO2)4) with H2SO4 (molar ratio 1:2); dissolving product in boiling H2O under Ar; addn. of excess Ba(ClO4)2*3H2O with stirring; cooling, filtering off ppt. of BaSO4; evapg. filtrate to min. vol. and passing through ion exchange column;; elution with H2O, 0.05 M and 0.5 M HClO4; adjusting HClO4-eluates to pH7 with aq. KOH-soln. (Ar), filtering, evapg. to dryness and drying in vac. desiccator (P2O5); dissolving in min. of abs. C2H5OH, filtering and evapg. to dryness; elem. anal.;;

Reference yield: 80.0%

tetra[μ-acetato-bis(methanol)]dirhodium + adenosine-5'-monophosphate disodium salt (4578-31-8) → dirhodium tetracetate dihydrate (917499-87-7,29998-99-0) + tetrakis-μ-acetato-dirhodium(II) adenosine-5'-monophosphate adduct

Guidance literature:

In water; slight excess of nucleotide, stirring for 5 h (dissoln.); pptn. on acetone addn.; elem. anal.;

DOI:10.1039/DT9790000596

Reference yield: 80.0%

tetra[μ-acetato-bis(methanol)]dirhodium + adenosine-5'-triphosphate disodium salt → dirhodium tetracetate dihydrate (917499-87-7,29998-99-0) + tetrakis-μ-acetato-dirhodium(II) adenosine-5'-triphosphate adduct

Guidance literature:

In water; slight excess of nucleotide, stirring for 5 h (dissoln.); pptn. on acetone addn.; elem. anal.;

DOI:10.1039/DT9790000596

upstream raw materials:

H₁₆N₅Rh⁽²⁺⁾

acetic acid

adenosine-5'-monophosphate disodium salt