ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate

Base Information

• Chemical Name: ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate
• CAS No.: 332143-57-4
• Molecular Formula: C₂₄H₂₂BrNO₂S₂
• Molecular Weight: 500.48
• Mol file: 332143-57-4.mol

Synonyms:ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate

Chemical Property of ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate

There total 3 articles about ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

chloroformic acid ethyl ester (541-41-3) + (2,2-bis-phenylsulfanyl-vinyl)-(2-bromo-benzyl)-amine (332143-49-4) → ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate (332143-57-4)

Guidance literature:

With N,N-diethylaniline; In benzene; Heating;

DOI:10.1016/S0040-4039(00)02138-9

Reference yield:

2-bromobenzylamine (3959-05-5) → ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate (332143-57-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 97 percent / MgSO₄ / diethyl ether / 15 h / 20 °C

2: 72 percent / N,N-diethylaniline / benzene / 20 h / Heating

With magnesium sulfate; N,N-diethylaniline; In diethyl ether; benzene;

DOI:10.1021/jo030177m

Reference yield:

Bis(phenylsulfanyl)acetaldehyde (153823-24-6) → ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate (332143-57-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 97 percent / MgSO₄ / diethyl ether / 15 h / 20 °C

2: 72 percent / N,N-diethylaniline / benzene / 20 h / Heating

With magnesium sulfate; N,N-diethylaniline; In diethyl ether; benzene;

DOI:10.1021/jo030177m

upstream raw materials:

chloroformic acid ethyl ester

(2,2-bis-phenylsulfanyl-vinyl)-(2-bromo-benzyl)-amine

2-bromobenzylamine

Bis(phenylsulfanyl)acetaldehyde