3-METHYL-1-DODECYN-3-OL

Base Information

• Chemical Name: 3-METHYL-1-DODECYN-3-OL
• CAS No.: 24424-78-0
• Molecular Formula: C13H24 O
• Molecular Weight: 196.333
• Hs Code.: 2905290000
• Mol file: 24424-78-0.mol

Synonyms:3-Methyl-1-dodecyn-3-ol

Chemical Property of 3-METHYL-1-DODECYN-3-OL

Chemical Property:

• Vapor Pressure: 0.013mmHg at 25°C
• Refractive Index: 1.4470
• Boiling Point: 229.4°Cat760mmHg
• PKA: 13.31±0.29(Predicted)
• Flash Point: 93.2°C
• PSA: 20.23000
• Density: 0.874g/cm³
• LogP: 3.51130

Purity/Quality:

99% ^*data from raw suppliers

3-METHYL-1-DODECYN-3-OL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 20/21-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-METHYL-1-DODECYN-3-OL

There total 5 articles about 3-METHYL-1-DODECYN-3-OL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

methyl nonyl ketone (112-12-9) + trimethylsilylacetylene (1066-54-2) → 3-methyldodec-1-yn-3-ol (24424-78-0)

Guidance literature:

methyl nonyl ketone; trimethylsilylacetylene; With n-butyllithium; In tetrahydrofuran; at -78 ℃;

With potassium carbonate; In methanol; at 20 ℃;

DOI:10.1021/acs.orglett.7b02624

Reference yield:

methyl nonyl ketone (112-12-9) → 3-methyldodec-1-yn-3-ol (24424-78-0)

Guidance literature:

With diethyl ether; sodium amide; nachfolgenden Einleiten von Acetylen bei 0grad unter etwas Ueberdruck;

DOI:10.1111/j.1744-7348.2002.tb00202.x

Reference yield:

methyl nonyl ketone (112-12-9) + acetylene (74-86-2,25067-58-7) → 3-methyldodec-1-yn-3-ol (24424-78-0)

Guidance literature:

With potassium hydroxide; diethyl ether;

upstream raw materials:

methyl nonyl ketone

acetylene

diethyl ether

trimethylsilylacetylene

Refernces