trans-{bis[(4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl)ethyne]bis(tri-n-butylphosphine)}platinum

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Chemical Name:trans-{bis[(4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl)ethyne]bis(tri-n-butylphosphine)}platinum
CAS No.:1429466-11-4
Molecular Formula:C₆₂H₈₄O₂P₂Pt
Molecular Weight:1118.38
Hs Code.:

Synonyms:trans-{bis[(4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl)ethyne]bis(tri-n-butylphosphine)}platinum

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Chemical Property of trans-{bis[(4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl)ethyne]bis(tri-n-butylphosphine)}platinum

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Technology Process of trans-{bis[(4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl)ethyne]bis(tri-n-butylphosphine)}platinum

There total 6 articles about trans-{bis[(4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl)ethyne]bis(tri-n-butylphosphine)}platinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 54.0%

: 15391-01-2,15076-72-9,15390-92-8
trans-dichloro-bis(tri-n-butylphosphine)platinum(II)

: 1429466-27-2
{4-[2-(4-ethynyl-3,5-dimethylphenyl)ethynyl]phenyl}methanol

: 1429466-11-4
trans-{bis[(4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl)ethyne]bis(tri-n-butylphosphine)}platinum

Guidance literature:: With copper(l) iodide; triethylamine; In tetrahydrofuran; at 70 ℃; for 4h;
DOI:10.1016/j.tetlet.2013.02.105

Reference yield:

: 1429466-23-8
4-iodo-2,6-dimethylphenyl trifluoromethanesulfonate

: 1429466-11-4
trans-{bis[(4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl)ethyne]bis(tri-n-butylphosphine)}platinum

Guidance literature:: Multi-step reaction with 4 steps

1: triethylamine; bis(triphenylphosphine)palladium(II) dichloride; copper(l) iodide / tetrahydrofuran

2: bis(triphenylphosphine)palladium(II) dichloride; copper(l) iodide; lithium chloride; diethylamine / N,N-dimethyl-formamide / 18 h / 50 °C

3: potassium carbonate / methanol / 1 h

4: triethylamine; copper(l) iodide / tetrahydrofuran / 4 h / 70 °C

With copper(l) iodide; bis(triphenylphosphine)palladium(II) dichloride; potassium carbonate; diethylamine; triethylamine; lithium chloride; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2013.02.105

Reference yield:

: 1429466-24-9
4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl trifluoromethanesulfonate

: 1429466-11-4
trans-{bis[(4-{2-[4-(hydroxymethyl)phenyl]ethynyl}-2,6-dimethylphenyl)ethyne]bis(tri-n-butylphosphine)}platinum

Guidance literature:: Multi-step reaction with 3 steps

1: bis(triphenylphosphine)palladium(II) dichloride; copper(l) iodide; lithium chloride; diethylamine / N,N-dimethyl-formamide / 18 h / 50 °C

2: potassium carbonate / methanol / 1 h

3: triethylamine; copper(l) iodide / tetrahydrofuran / 4 h / 70 °C

With copper(l) iodide; bis(triphenylphosphine)palladium(II) dichloride; potassium carbonate; diethylamine; triethylamine; lithium chloride; In tetrahydrofuran; methanol; N,N-dimethyl-formamide;
DOI:10.1016/j.tetlet.2013.02.105