Wym3TH44BC

Base Information

Chemical Name:Wym3TH44BC
CAS No.:29873-99-2
Molecular Formula:C₁₅H₂₄
Molecular Weight:204.356
Hs Code.:
UNII:WYM3TH44BC
DSSTox Substance ID:DTXSID00881215
Wikidata:Q76422757
Mol file:29873-99-2.mol

Synonyms:WYM3TH44BC;29873-99-2;(-)-gamma-Elemene;gamma-Elemene, (-)-;UNII-WYM3TH44BC;o-Menth-8-ene, 4-isopropylidene-1-vinyl-, (-)-;(1R,2R)-1-Ethenyl-1-methyl-2-(1-methylethenyl)-4-(1-methylethylidene)cyclohexane;Cyclohexane, 1-ethenyl-1-methyl-2-(1-methylethenyl)-4-(1-methylethylidene)-, (1R,2R)-;Cyclohexane, 1-ethenyl-1-methyl-2-(1-methylethenyl)-4-(1-methylethylidene)-, (1R-trans)-;.gamma.-Elemene;(-)-.gamma.-Elemene;DTXSID00881215;.GAMMA.-ELEMENE, (-)-;NS00096356;1-ethenyl-1-methyl-2-(1-methylethenyl)-4-(1-methylethylidene)-cyclohexane;(1R, 2R)-1-ethenyl-1-methyl-4-propan-2-ylidene-2-prop-1-en-2-ylcyclohexane;(-)-|A-elemene,1-ethenyl-1-methyl-2-(1-methylethenyl)-4-(1-methylethylidene)-cyclohexane,|A-elemene

Suppliers and Price of Wym3TH44BC

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 9 raw suppliers

Chemical Property of Wym3TH44BC

Chemical Property:

Vapor Pressure:0.0225mmHg at 25°C
Refractive Index:1.511
Boiling Point:258.2°Cat760mmHg
Flash Point:101.3°C
Density:0.876g/cm³
XLogP3:5.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:204.187800766
Heavy Atom Count:15
Complexity:302

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=C1CCC(C(C1)C(=C)C)(C)C=C)C
Isomeric SMILES:CC(=C1CC[C@]([C@H](C1)C(=C)C)(C)C=C)C
Uses γ-Elemene is an essential oil extracted from plant source and which exhibits pesticidal activities

Technology Process of Wym3TH44BC

There total 6 articles about Wym3TH44BC which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1273149-94-2
(+)-(5S,10S)-elema-1,3,7,11⁽¹²⁾-tetraene

: 3242-08-8,29873-99-2,30824-67-0,32663-56-2,38906-87-5,57172-50-6,58865-70-6,73246-02-3
γ–elemene

Guidance literature:: (+)-(5S,10S)-elema-1,3,7,11⁽¹²⁾-tetraene; With ammonia; sodium; In tetrahydrofuran; at -78 ℃; for 0.416667h;

With tert-butyl alcohol; In tetrahydrofuran; for 0.0833333h;
DOI:10.1039/c0ob00467g

Reference yield:

: 6902-91-6
germacrone

: 3242-08-8,29873-99-2,30824-67-0,32663-56-2,38906-87-5,57172-50-6,58865-70-6,73246-02-3
γ–elemene

Guidance literature:: Multi-step reaction with 3 steps

1.1: (3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydro-2H-pyrrolo[2,1-e]azaborole; borane-THF / tetrahydrofuran; toluene / Cooling with ice; Inert atmosphere

2.1: bis(benzonitrile)palladium(II) dichloride / toluene / 1.75 h / Inert atmosphere; Reflux

3.1: ammonia; sodium / tetrahydrofuran / 0.42 h / -78 °C

3.2: 0.08 h

With bis(benzonitrile)palladium(II) dichloride; borane-THF; (3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydro-2H-pyrrolo[2,1-e]azaborole; ammonia; sodium; In tetrahydrofuran; toluene; 2.1: Cope rearrangement;
DOI:10.1039/c0ob00467g

Reference yield:

: 90988-53-7
(3E,7E)-3,7-dimethyl-10-(1-methylethylidene)-3,7-cyclodecanedien-1-ol

: 3242-08-8,29873-99-2,30824-67-0,32663-56-2,38906-87-5,57172-50-6,58865-70-6,73246-02-3
γ–elemene

Guidance literature:: Multi-step reaction with 2 steps

1.1: bis(benzonitrile)palladium(II) dichloride / toluene / 1.75 h / Inert atmosphere; Reflux

2.1: ammonia; sodium / tetrahydrofuran / 0.42 h / -78 °C

2.2: 0.08 h

With bis(benzonitrile)palladium(II) dichloride; ammonia; sodium; In tetrahydrofuran; toluene; 1.1: Cope rearrangement;
DOI:10.1039/c0ob00467g