1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol

Base Information

Chemical Name:1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol
CAS No.:97119-76-1
Molecular Formula:C₃₆H₄₁NO₅
Molecular Weight:575.662
Hs Code.:

1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-<D2>benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol

Synonyms:1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol

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Chemical Property of 1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol

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Technology Process of 1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol

There total 16 articles about 1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 1D-(1N,2,4/3,5,6)-1-Azido-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol

: 97119-76-1
1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol

Guidance literature:: With sodium tetrahydroborate; nickel dichloride; In ethanol;

Reference yield:

: 51271-29-5
[1',1'-2H₂]benzyl bromide

: 97119-76-1
1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol

Guidance literature:: Multi-step reaction with 13 steps

1: 94 percent / 1) NaH / dimethylformamide / 1) 2 h, 0 deg C, 2) 5 h, room temp.

2: 81 percent / 98percent acetic acid / 30 °C

3: 91 percent / 1) NaH / dimethylformamide / 1) 2 h, 0 deg C, 2) 5 h, room temp.

4: 91 percent / acetic acid / tetrahydrofuran; H₂O / 60 °C

5: p-toluenesulfonic acid / toluene / 0.17 h / Ambient temperature

6: 90percent acetic acid / toluene / 0.08 h

7: 89 percent / ethyldiisopropylamine / CH₂Cl₂

8: 1 N NaOCH₃ / methanol

9: 91 percent / 1) NaH / dimethylformamide / 1) 2 h, 0 deg C, 2) 5 h, room temp.

10: 95 percent / 3 N HCl / tetrahydrofuran / 10 h / 60 °C

11: 89 percent / pyridine / CH₂Cl₂ / -40 °C

12: 52 percent / NaN₃ / dimethylformamide / Ambient temperature

13: 79 percent / 4percent NiCl₂-solution, NaBH₄ / ethanol

With pyridine; hydrogenchloride; sodium tetrahydroborate; sodium azide; sodium methylate; sodium hydride; toluene-4-sulfonic acid; acetic acid; N-ethyl-N,N-diisopropylamine; nickel dichloride; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene;

Reference yield:

: 86845-47-8,86853-27-2
1L-1-Desoxy-1-C-hydroxymethyl-2,3:4,5-di-O-isopropyliden-6-O-methyl-myo-inosit

: 97119-76-1
1D-(1N,2,4/3,5,6)-1-Amino-2,3,6,7-tetra-O-benzyl-5-C-(hydroxymethyl)-4-O-methyl-2,3,4,6-cyclohexantetrol

Guidance literature:: Multi-step reaction with 13 steps

1: 94 percent / 1) NaH / dimethylformamide / 1) 2 h, 0 deg C, 2) 5 h, room temp.

2: 81 percent / 98percent acetic acid / 30 °C

3: 91 percent / 1) NaH / dimethylformamide / 1) 2 h, 0 deg C, 2) 5 h, room temp.

4: 91 percent / acetic acid / tetrahydrofuran; H₂O / 60 °C

5: p-toluenesulfonic acid / toluene / 0.17 h / Ambient temperature

6: 90percent acetic acid / toluene / 0.08 h

7: 89 percent / ethyldiisopropylamine / CH₂Cl₂

8: 1 N NaOCH₃ / methanol

9: 91 percent / 1) NaH / dimethylformamide / 1) 2 h, 0 deg C, 2) 5 h, room temp.

10: 95 percent / 3 N HCl / tetrahydrofuran / 10 h / 60 °C

11: 89 percent / pyridine / CH₂Cl₂ / -40 °C

12: 52 percent / NaN₃ / dimethylformamide / Ambient temperature

13: 79 percent / 4percent NiCl₂-solution, NaBH₄ / ethanol

With pyridine; hydrogenchloride; sodium tetrahydroborate; sodium azide; sodium methylate; sodium hydride; toluene-4-sulfonic acid; acetic acid; N-ethyl-N,N-diisopropylamine; nickel dichloride; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene;