2-(trimethylsilyl)ethyl 2-O-benzylidene-3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside

Base Information

Chemical Name:2-(trimethylsilyl)ethyl 2-O-benzylidene-3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside
CAS No.:1422649-97-5
Molecular Formula:C₂₈H₃₈O₆Si
Molecular Weight:498.692
Hs Code.:

Synonyms:2-(trimethylsilyl)ethyl 2-O-benzylidene-3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside

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Chemical Property of 2-(trimethylsilyl)ethyl 2-O-benzylidene-3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside

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Technology Process of 2-(trimethylsilyl)ethyl 2-O-benzylidene-3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside

There total 5 articles about 2-(trimethylsilyl)ethyl 2-O-benzylidene-3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1422649-98-6
C₂₁H₃₂O₆Si

: 100-39-0
benzyl bromide

: 1422649-97-5
2-(trimethylsilyl)ethyl 2-O-benzylidene-3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃; for 0.5h;
DOI:10.1007/s11164-013-1060-0

Reference yield:

: 39698-00-5
acetyl 2,4,6-tri-O-acetyl-3-O-allyl-β-D-glucopyranoside

: 1422649-97-5
2-(trimethylsilyl)ethyl 2-O-benzylidene-3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: acetic acid; hydrogen bromide / dichloromethane / 1.5 h / 20 °C

2: mercury(II) oxide; mercury dibromide / dichloromethane / 18 h / 20 °C

3: sodium methylate; methanol / 20 °C

4: camphor-10-sulfonic acid / acetonitrile / 20 °C

5: sodium hydride / N,N-dimethyl-formamide / 0.5 h / 0 °C

With methanol; camphor-10-sulfonic acid; hydrogen bromide; sodium methylate; sodium hydride; acetic acid; mercury dibromide; mercury(II) oxide; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1007/s11164-013-1060-0

Reference yield:

: Acetic acid (2R,3R,4S,5R)-5-acetoxy-2-acetoxymethyl-4-allyloxy-6-bromo-tetrahydro-pyran-3-yl ester

: 1422649-97-5
2-(trimethylsilyl)ethyl 2-O-benzylidene-3-O-allyl-4,6-O-benzylidene-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: mercury(II) oxide; mercury dibromide / dichloromethane / 18 h / 20 °C

2: sodium methylate; methanol / 20 °C

3: camphor-10-sulfonic acid / acetonitrile / 20 °C

4: sodium hydride / N,N-dimethyl-formamide / 0.5 h / 0 °C

With methanol; camphor-10-sulfonic acid; sodium methylate; sodium hydride; mercury dibromide; mercury(II) oxide; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1007/s11164-013-1060-0