Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))={Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}

Base Information

• Chemical Name: Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))={Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}
• CAS No.: 150771-09-8
• Molecular Formula: C₂₉H₄₁P₂RhS
• Molecular Weight: 586.564
• Mol file: 150771-09-8.mol

Synonyms:Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))={Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}

Chemical Property of Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))={Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))={Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}

There total 2 articles about Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))={Rh(C₈H₁₂)(CH(P(C₆H₅)2)(P(S)(C(CH₃)3)2))} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

Rh(C8H12)(CH2(P(C6H5)2)(P(S)(C(CH3)3)2))(1+)*ClO4(1-)*CH2Cl2={Rh(C8H12)(CH2(P(C6H5)2)(P(S)(C(CH3)3)2))}(ClO4)*CH2Cl2 (150771-13-4) → Rh(C8H12)(CH(P(C6H5)2)(P(S)(C(CH3)3)2))={Rh(C8H12)(CH(P(C6H5)2)(P(S)(C(CH3)3)2))} (150771-09-8)

Guidance literature:

With NaH; In tetrahydrofuran; (at room temp. under N2); NaH is added to a stirred soln. of the Rh complex; after 2 h filtn., removal of the solvent in vac., recrystn. of the residue (hexane), elem. anal.;

DOI:10.1016/0022-328X(93)83192-X

Reference yield:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + Li(1+)*CH(P(C6H5)2)(P(S)(C(CH3)3)2)(1-)=Li{CH(P(C6H5)2)(P(S)(C(CH3)3)2)} → Rh(C8H12)(CH(P(C6H5)2)(P(S)(C(CH3)3)2))={Rh(C8H12)(CH(P(C6H5)2)(P(S)(C(CH3)3)2))} (150771-09-8)

Guidance literature:

In tetrahydrofuran; (at room temp., under N2); dropwise addn. of the Li-ligand in THF to a stirred soln. of the starting complex in THF; volume is reduced after 3 h by removal of solvent in vac.;

DOI:10.1016/0022-328X(93)83192-X

upstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))⁽¹⁺⁾*ClO₄^(1-)*CH₂Cl₂={Rh(C₈H₁₂)(CH₂(P(C₆H₅)2)(P(S)(C(CH₃)3)2))}(ClO₄)*CH₂Cl₂