allyl O-(2,3,67-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Base Information

• Chemical Name: allyl O-(2,3,67-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside
• CAS No.: 171411-83-9
• Molecular Formula: C₁₁₁H₁₁₈O₂₁
• Molecular Weight: 1788.15
• Mol file: 171411-83-9.mol

Synonyms:allyl O-(2,3,67-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Chemical Property of allyl O-(2,3,67-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of allyl O-(2,3,67-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside

There total 3 articles about allyl O-(2,3,67-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

allyl O-(2,3,6-tri-O-benzyl-4-O-p-nitrobenzenesulfonyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside → allyl O-(2,3,67-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside (171411-83-9)

Guidance literature:

With lithium aluminium tetrahydride; In 1,2-dimethoxyethane; for 0.5h;

DOI:10.1246/bcsj.68.2331

Reference yield: 36.0%

allyl O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (171411-82-8) + 4-Nitrobenzenesulfonyl chloride (98-74-8) → allyl O-(2,3,4-tri-O-benzyl-6-O-p-nitrobenzenesulfonyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (171411-84-0) + allyl O-(2,3,67-tri-O-benzyl-β-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside + allyl O-(2,3,67-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside (171411-83-9)

Guidance literature:

With N,N-dimethyl acetamide; silver trifluoromethanesulfonate; triethylamine; In dichloromethane; at -40 - 0 ℃;

DOI:10.1246/bcsj.68.2331

Reference yield: 18.0%

4-O-acetyl-2,3,6-tri-O-benzyl-β-D-glucopyranoside (84218-71-3,114079-12-8,127874-07-1,127875-24-5,127875-31-4,127875-37-0) + allyl O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (171411-82-8) → allyl O-(2,3,4-tri-O-benzyl-6-O-p-nitrobenzenesulfonyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside (171411-84-0) + allyl O-(2,3,67-tri-O-benzyl-β-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside + allyl O-(2,3,67-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>6)-O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-2,3,6-tri-O-benzyl-β-D-glucopyranoside (171411-83-9)

Guidance literature:

With N,N-dimethyl acetamide; silver trifluoromethanesulfonate; triethylamine; 4-Nitrobenzenesulfonyl chloride; In dichloromethane; at -40 - 0 ℃;

DOI:10.1246/bcsj.68.2331

upstream raw materials:

4-O-acetyl-2,3,6-tri-O-benzyl-β-D-glucopyranoside

allyl O-(2,3,4-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-O-(2,3,6-tri-O-benzyl-α-D-glucopyranosyl)-(1<*>4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

4-Nitrobenzenesulfonyl chloride