bis(diphenylphosphinomethyl)phenylphosphine

Base Information

• Chemical Name: bis(diphenylphosphinomethyl)phenylphosphine
• CAS No.: 2071-24-1
• Molecular Formula: C₃₂H₂₉P₃
• Molecular Weight: 506.504
• Mol file: 2071-24-1.mol

Synonyms:bis(diphenylphosphinomethyl)phenylphosphine

Chemical Property of bis(diphenylphosphinomethyl)phenylphosphine

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(diphenylphosphinomethyl)phenylphosphine

There total 2 articles about bis(diphenylphosphinomethyl)phenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dichlorophenylphosphine (644-97-3) + diphenyl(trimethylsilylmethyl)phosphane (4451-96-1) → bis(diphenylphosphinomethyl)phenylphosphine (2071-24-1)

Guidance literature:

Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2015.07.017

Reference yield:

→ bis(diphenylphosphinomethyl)phenylphosphine (2071-24-1)

Guidance literature:

aus Bis--phenyl-phosphin, Diphenyl-phosphin bei 180grad;

DOI:10.1002/hlca.19650480507

Reference yield: 86.0%

Ag(tetrahydrothiophene)ClO4 + Pt(PPh3)2(CCC6H2(OMe)3-3,4,5)2 (1253784-30-3) + bis(diphenylphosphinomethyl)phenylphosphine (2071-24-1) → [PtAg2(bis(diphenylphosphinomethyl)phenylphosphine)2(1-ethynyl-3,4,5-trimethoxybenzene(1-))2](perchlorate)2

Guidance literature:

Ag(tetrahydrothiophene)ClO₄; bis(diphenylphosphinomethyl)phenylphosphine; In dichloromethane; for 0.5h; Inert atmosphere; Schlenk technique;

Pt(PPh₃)₂(CCC₆H₂(OMe)₃-3,4,5)₂ ; In dichloromethane; at 20 ℃; for 4h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic4000457

upstream raw materials:

Dichlorophenylphosphine

diphenyl(trimethylsilylmethyl)phosphane

Downstream raw materials:

Pd(dpmp)2Cl₂

HgCl₂(dpmp)

Refernces