biphenyl-4-yl(cyclohexyl)sulfane

Base Information

• Chemical Name: biphenyl-4-yl(cyclohexyl)sulfane
• CAS No.: 129125-87-7
• Molecular Formula: C₁₈H₂₀S
• Molecular Weight: 268.423
• Mol file: 129125-87-7.mol

Synonyms:biphenyl-4-yl(cyclohexyl)sulfane

Chemical Property of biphenyl-4-yl(cyclohexyl)sulfane

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of biphenyl-4-yl(cyclohexyl)sulfane

There total 4 articles about biphenyl-4-yl(cyclohexyl)sulfane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Cyclohexanethiol (1569-69-3) + 4-iodo-biphenyl (1591-31-7) → biphenyl-4-yl(cyclohexyl)sulfane (129125-87-7)

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; In water; at 50 ℃; for 24h; chemoselective reaction; Inert atmosphere; Sealed tube;

DOI:10.1039/c2ob06795a

Reference yield: 68.0%

Cyclohexanethiol (1569-69-3) + C24H17S2(1+)*BF4(1-) → biphenyl-4-yl(cyclohexyl)sulfane (129125-87-7)

Guidance literature:

With copper(I) thiophene-2-carboxylate; [4,4′-bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis{3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC}iridium(III) hexafluorophosphate; sodium hydride; In acetonitrile; mineral oil; at 30 ℃; for 16h; Inert atmosphere; Irradiation;

DOI:10.1002/anie.201908718

Reference yield: 5.0%

biphenyl (92-52-4,1594-86-1) + 1-oxa-4-thiaspiro-<4,5>decan-2-one (1564-39-2) → 2-cyclohexylthioacetic acid (52363-15-2) + biphenyl-4-yl(cyclohexyl)sulfane (129125-87-7) + 6'-phenylspiro-4'-one (141622-55-1) + <<1-(biphenyl)cyclohexyl>thio>acetic acid (141622-69-7)

Guidance literature:

With aluminium trichloride; In carbon disulfide; for 24h; Further byproducts given; Ambient temperature;

upstream raw materials:

biphenyl

1-oxa-4-thiaspiro-<4,5>decan-2-one

Cyclohexanethiol

4-iodo-biphenyl

Refernces

• 1、 Xu, Hua-Jian,Liang, Yu-Feng,Zhou, Xin-Feng,Feng, Yi-Si. "Efficient recyclable CuI-nanoparticle-catalyzed S-arylation of thiols with aryl halides on water under mild conditions". supporting information; experimental part. p. 2562 - 2568. Retrieved 2012/04/23.