bis(μ-chloro)(μ-hydrido)dihydridotetrakis(triphenylphosphine)diiridium(III) hexafluoroantimonate

Base Information

Chemical Name:bis(μ-chloro)(μ-hydrido)dihydridotetrakis(triphenylphosphine)diiridium(III) hexafluoroantimonate
CAS No.:106880-36-8
Molecular Formula:C₇₂H₆₃Cl₂Ir₂P₄*F₆Sb
Molecular Weight:1743.27
Hs Code.:

Synonyms:bis(μ-chloro)(μ-hydrido)dihydridotetrakis(triphenylphosphine)diiridium(III) hexafluoroantimonate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(μ-chloro)(μ-hydrido)dihydridotetrakis(triphenylphosphine)diiridium(III) hexafluoroantimonate

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Technology Process of bis(μ-chloro)(μ-hydrido)dihydridotetrakis(triphenylphosphine)diiridium(III) hexafluoroantimonate

There total 2 articles about bis(μ-chloro)(μ-hydrido)dihydridotetrakis(triphenylphosphine)diiridium(III) hexafluoroantimonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 110077-68-4,89509-77-3
{IrH₂(acetone)2(PPh₃)2}SbF₆

: 106880-36-8
bis(μ-chloro)(μ-hydrido)dihydridotetrakis(triphenylphosphine)diiridium(III) hexafluoroantimonate

: tris(μ-chloro)dihydridotetrakis(triphenylphosphine)diiridium(III) hexafluoroantimonate

Guidance literature:: With hydrogenchloride; In dichloromethane; stirred with excess conc. HCl for 10 min; evapd., washed with H2O, Et2O, dissolved in Me2CO, stirred briefly with NaSbF6, evapd., CH2Cl2 added, soln. filtered, addn. of acetone and Et2O to the filtrate pptd. the 3-μ-Cl complex as 2 stereoisomers ((1)H NMR data); elem. anal.;
DOI:10.1021/om00147a003

Reference yield:

: 53470-69-2
pentahydridobis(triphenylphosphine)iridium(III)

: 106880-36-8
bis(μ-chloro)(μ-hydrido)dihydridotetrakis(triphenylphosphine)diiridium(III) hexafluoroantimonate

Guidance literature:: With hydrogenchloride; In dichloromethane; treated with conc. HCl; evapd., washed with H2O, Et2O, dissolved in Me2CO, stirred briefly with NaSbF6, evapd., CH2Cl2 added, soln. filtered, addn. of acetone and Et2O to the filtrate pptd. the product; (1)H NMR identification;
DOI:10.1021/om00147a003