pentahydridobis(triphenylphosphine)iridium(III)

Base Information

Chemical Name:pentahydridobis(triphenylphosphine)iridium(III)
CAS No.:53470-69-2
Molecular Formula:C₃₆H₃₅IrP₂
Molecular Weight:721.841
Hs Code.:

Synonyms:pentahydridobis(triphenylphosphine)iridium(III)

Suppliers and Price of pentahydridobis(triphenylphosphine)iridium(III)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of pentahydridobis(triphenylphosphine)iridium(III)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of pentahydridobis(triphenylphosphine)iridium(III)

There total 6 articles about pentahydridobis(triphenylphosphine)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 16940-66-2
sodium tetrahydroborate

: 31781-78-9
IrH(η⁴-COD)(PPh₃)₂

: 53470-69-2
pentahydridobis(triphenylphosphine)iridium(III)

Guidance literature:: In ethanol; (Ar); stirred at room temp. for 18 h; filtered off; repeatedly washed (ethanol); dried in vacuo; elem. anal.;

Reference yield: 60.0%

: 16971-01-0,24846-85-3,28060-70-0,77448-67-0
mer-IrHCl₂(PPh₃)3

: 16971-01-0,24846-85-3,28060-70-0,77448-67-0
mer-IrHCl₂(PPh₃)3

: 7732-18-5
water

: 1333-74-0
hydrogen

: potassium hydride

: K⁽¹⁺⁾*IrH₃(P(C₆H₅)3)2(P(C₆H₅)2)^(1-)=K(IrH₃(P(C₆H₅)3)2(P(C₆H₅)2))

: 53470-69-2
pentahydridobis(triphenylphosphine)iridium(III)

Guidance literature:: In tetrahydrofuran; byproducts: KCl, HPPh2, KOH; High Pressure; standard Schlenk techniques; mixt. of THF, cis,mer- and trans,mer-Ir complex and KH (10 equiv.) held at 100°C under 75 atm H2 with stirring for 3 d in autoclave; cooled to room temp.; filtered; solid washed with THF; filtrate and washings combined; evapd. to dryness under reduced pressure; washed with distd. degassed H2O and THF; dried under vac.;
DOI:10.1021/ic0255149

Reference yield:

: 119787-62-1
(η5-indenyl)bis(triphenylphosphine)iridium(I)

: 53470-69-2
pentahydridobis(triphenylphosphine)iridium(III)

Guidance literature:: With H₂; In benzene-d6; byproducts: indene; reaction of Ir complex with H2 in C6D6 (20°C), standing (2 d);
DOI:10.1021/om00107a016