Rh₂(C₆H₄(PCH₃C₆H₅)2)2⁽²⁺⁾*2PF₆^(1-)*0.5CH₂Cl₂=Rh₂(C₆H₄(PCH₃C₆H₅)2)2(PF₆)2*0.5CH₂Cl₂

Base Information

• Chemical Name: Rh₂(C₆H₄(PCH₃C₆H₅)2)2⁽²⁺⁾*2PF₆^(1-)*0.5CH₂Cl₂=Rh₂(C₆H₄(PCH₃C₆H₅)2)2(PF₆)2*0.5CH₂Cl₂
• CAS No.: 101052-79-3
• Molecular Formula: 0CH₂Cl₂*C₄₀H₄₀P₄Rh₂*2F₆P
• Molecular Weight: 1182.86

Synonyms:Rh₂(C₆H₄(PCH₃C₆H₅)2)2⁽²⁺⁾*2PF₆^(1-)*0.5CH₂Cl₂=Rh₂(C₆H₄(PCH₃C₆H₅)2)2(PF₆)2*0.5CH₂Cl₂

Chemical Property of Rh₂(C₆H₄(PCH₃C₆H₅)2)2⁽²⁺⁾*2PF₆^(1-)*0.5CH₂Cl₂=Rh₂(C₆H₄(PCH₃C₆H₅)2)2(PF₆)2*0.5CH₂Cl₂

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Technology Process of Rh₂(C₆H₄(PCH₃C₆H₅)2)2⁽²⁺⁾*2PF₆^(1-)*0.5CH₂Cl₂=Rh₂(C₆H₄(PCH₃C₆H₅)2)2(PF₆)2*0.5CH₂Cl₂

There total 1 articles about Rh₂(C₆H₄(PCH₃C₆H₅)2)2⁽²⁺⁾*2PF₆^(1-)*0.5CH₂Cl₂=Rh₂(C₆H₄(PCH₃C₆H₅)2)2(PF₆)2*0.5CH₂Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(R*,R*)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone (101052-77-1) → Rh2(C6H4(PCH3C6H5)2)2(2+)*2PF6(1-)*0.5CH2Cl2=Rh2(C6H4(PCH3C6H5)2)2(PF6)2*0.5CH2Cl2 (101052-79-3)

Guidance literature:

With hydrogen; In dichloromethane; a soln. of Rh complex was stirred under 1 atm H2 for 15 h; filtn., recrystallization from hot CH2Cl2, elem. anal.;

DOI:10.1021/om00136a029

Reference yield: 65.0%

Rh2(C6H4(PCH3C6H5)2)2(2+)*2PF6(1-)*0.5CH2Cl2=Rh2(C6H4(PCH3C6H5)2)2(PF6)2*0.5CH2Cl2 (101052-79-3) + methyl (Z)-2-(acetylamino)-3-phenylpropenoate (60676-51-9) → Rh(C6H4(PCH3C6H5)2)(C6H5CHC(NHCOCH3)CO2CH3)(1+)*PF6(1-)=Rh(C6H4(PCH3C6H5)2)(C6H5CHC(NHCOCH3)CO2CH3)(PF6)

Guidance literature:

In acetone; suspn. of complex and ligand in acetone was stirred under Ar until all of the Rh dimer had dissolved; addn. of Et2O, as monitored by (1)H NMR a pair of diastereomers in the ratio 1.2/1, elem. anal.;

DOI:10.1021/om00136a029

upstream raw materials:

(R*,R*)-(bicyclo[2.2.1]hepta-2,5-diene)[1,2-phenylenebis(methylphenylphosphine)]rhodium(I) hexafluorophosphate diacetone

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