allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside

Base Information

• Chemical Name: allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside
• CAS No.: 84730-33-6
• Molecular Formula: C₃₄H₃₇NO₈
• Molecular Weight: 587.67
• Mol file: 84730-33-6.mol

Synonyms:allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside

Chemical Property of allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside

There total 2 articles about allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

2-acetamido-2-deoxy-6-O-trityl-β-D-glucopyranoside (65947-35-5) + acetic anhydride (108-24-7) → allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside (84730-33-6)

Guidance literature:

In pyridine; Ambient temperature;

DOI:10.1016/0008-6215(83)88266-4

Reference yield:

allyl 2-acetamido-2-deoxy-β-D-glucopyranoside (54400-75-8,64650-83-5,88903-97-3,116347-86-5,140849-88-3,144300-01-6,54400-77-0) + acetic anhydride (108-24-7) + trityl chloride (76-83-5) → allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside (84730-33-6)

Guidance literature:

With dmap; Yield given. Multistep reaction; 1.) pyridine, r.t., 2 d; 2.) pyridine, 24 h;

DOI:10.1016/0008-6215(83)88266-4

Reference yield: 95.0%

allyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside (84730-33-6) → (Z)-prop-1-enyl 2-acetamido-3,4-di-O-acetyl-2-deoxy-6-O-trityl-β-D-glucopyranoside

Guidance literature:

With tris(triphenylphosphine)ruthenium(II) chloride; N-ethyl-N,N-diisopropylamine; In toluene; for 2h; Heating;

DOI:10.1139/v00-073

upstream raw materials:

2-acetamido-2-deoxy-6-O-trityl-β-D-glucopyranoside

acetic anhydride

allyl 2-acetamido-2-deoxy-β-D-glucopyranoside

trityl chloride

Downstream raw materials:

2-acetamido-2-deoxy-6-O-β-D-glucopyranosyl-D-glucopyranoside