methyl 3α-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)-5β-cholan-24-oate

Base Information

Chemical Name:methyl 3α-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)-5β-cholan-24-oate
CAS No.:835885-82-0
Molecular Formula:C₅₉H₇₆O₈
Molecular Weight:913.248
Hs Code.:

Synonyms:methyl 3α-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)-5β-cholan-24-oate

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Chemical Property of methyl 3α-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)-5β-cholan-24-oate

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Technology Process of methyl 3α-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)-5β-cholan-24-oate

There total 4 articles about methyl 3α-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)-5β-cholan-24-oate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 100-39-0
benzyl bromide

: 116939-40-3
methyl 3α-(β-D-glucopyranosyloxy)-5β-cholan-24-oate

: 835885-82-0
methyl 3α-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)-5β-cholan-24-oate

Guidance literature:: With potassium hydroxide; tetra-(n-butyl)ammonium iodide; In toluene; for 72h; Heating;
DOI:10.1135/cccc20041149

Reference yield:

: 1249-75-8,5405-42-5,15074-01-8,15074-02-9,20231-51-0,63814-53-9,106757-10-2,125412-30-8
methyl lithocholate

: 835885-82-0
methyl 3α-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)-5β-cholan-24-oate

Guidance literature:: Multi-step reaction with 3 steps

1: 50 percent / mercuric cyanide / acetonitrile / 5 h / Heating

2: 72 percent / NaOMe / methanol / 1 h / 20 °C

3: 40 percent / KOH; tetrabutylammonium iodide / toluene / 72 h / Heating

With potassium hydroxide; sodium methylate; mercury(II) cyanide; tetra-(n-butyl)ammonium iodide; In methanol; toluene; acetonitrile;
DOI:10.1135/cccc20041149

Reference yield:

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 835885-82-0
methyl 3α-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyloxy)-5β-cholan-24-oate

Guidance literature:: Multi-step reaction with 3 steps

1: 50 percent / mercuric cyanide / acetonitrile / 5 h / Heating

2: 72 percent / NaOMe / methanol / 1 h / 20 °C

3: 40 percent / KOH; tetrabutylammonium iodide / toluene / 72 h / Heating

With potassium hydroxide; sodium methylate; mercury(II) cyanide; tetra-(n-butyl)ammonium iodide; In methanol; toluene; acetonitrile;
DOI:10.1135/cccc20041149