1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-phenylvinyl)benzene

Base Information

• Chemical Name: 1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-phenylvinyl)benzene
• CAS No.: 1201909-50-3
• Molecular Formula: C₂₇H₂₄
• Molecular Weight: 348.488
• Mol file: 1201909-50-3.mol

Synonyms:1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-phenylvinyl)benzene

Chemical Property of 1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-phenylvinyl)benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-phenylvinyl)benzene

There total 2 articles about 1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-phenylvinyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1-dibromo-2,2-diphenylcyclopropane (17343-74-7) + hexa-1,5-dien-2-ylbenzene (7399-52-2) → 1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-phenylvinyl)benzene (1201909-50-3)

Guidance literature:

With tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide; In tetrahydrofuran; at 20 ℃; for 36h;

DOI:10.1021/ol902505p DOI:10.1021/ol902832s

Reference yield:

1,1-Diphenylethylene (530-48-3) → 1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-phenylvinyl)benzene (1201909-50-3)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium tert-butylate / pentane

2: tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide / tetrahydrofuran / 36 h / 20 °C

With potassium tert-butylate; tetra(n-butyl)ammonium hydrogensulfate; sodium hydroxide; In tetrahydrofuran; pentane;

DOI:10.1055/s-0030-1259715

Reference yield: 90.0%

1-(2-(2-(but-3-enyl)-2-phenylcyclopropylidene)-1-phenylvinyl)benzene (1201909-50-3) → 6-(diphenylmethylene)-1-phenylbicyclo[5.1.0]oct-3-ene

Guidance literature:

With di(rhodium)tetracarbonyl dichloride; carbon monoxide; In toluene; acetonitrile; at 100 ℃; for 1h; under 760.051 Torr;

DOI:10.1021/ol902505p

upstream raw materials:

1,1-dibromo-2,2-diphenylcyclopropane

hexa-1,5-dien-2-ylbenzene

1,1-Diphenylethylene

Downstream raw materials:

C₂₇H₂₄

4-(2-(2,2-diphenylvinylidene)-1-phenylcyclopropyl)butan-1-ol

C₂₇H₂₅BrO

C₂₇H₂₅IO