Technology Process of tris{4-[2-(4-hexyloxyphenyl)ethynyl]phenyl}tris[1,2,4]triazolo[4,3-a:4',3'-c:4'',3''-e][1,3,5]triazine
There total 4 articles about tris{4-[2-(4-hexyloxyphenyl)ethynyl]phenyl}tris[1,2,4]triazolo[4,3-a:4',3'-c:4'',3''-e][1,3,5]triazine which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
5-[4-(2(p-(hexyloxy)phenyl)ethynyl)phenyl]-2H-tetrazole;
With
pyridine;
In
5,5-dimethyl-1,3-cyclohexadiene;
for 0.5h;
Inert atmosphere;
1,3,5-trichloro-2,4,6-triazine;
In
5,5-dimethyl-1,3-cyclohexadiene;
for 1h;
Inert atmosphere;
Reflux;
DOI:10.1002/ejoc.201400088
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium azide; tetrachlorosilane / acetonitrile / 16 h / 50 °C / Inert atmosphere
2.1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tri-n-hexylamine; potassium carbonate / N,N-dimethyl-formamide; water / 85 °C / Inert atmosphere; Schlenk technique
3.1: pyridine / 5,5-dimethyl-1,3-cyclohexadiene / 0.5 h / Inert atmosphere
3.2: 1 h / Inert atmosphere; Reflux
With
pyridine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; sodium azide; tetrachlorosilane; tri-n-hexylamine; potassium carbonate;
In
5,5-dimethyl-1,3-cyclohexadiene; water; N,N-dimethyl-formamide; acetonitrile;
2.1: |Sonogashira Cross-Coupling;
DOI:10.1002/ejoc.201400088
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: triphenylphosphine; zinc / Inert atmosphere
1.2: Inert atmosphere
2.1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tri-n-hexylamine; potassium carbonate / N,N-dimethyl-formamide; water / 85 °C / Inert atmosphere; Schlenk technique
3.1: pyridine / 5,5-dimethyl-1,3-cyclohexadiene / 0.5 h / Inert atmosphere
3.2: 1 h / Inert atmosphere; Reflux
With
pyridine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; tri-n-hexylamine; potassium carbonate; triphenylphosphine; zinc;
In
5,5-dimethyl-1,3-cyclohexadiene; water; N,N-dimethyl-formamide;
1.1: |Corey-Fuchs Alkyne Synthesis / 1.2: |Corey-Fuchs Alkyne Synthesis / 2.1: |Sonogashira Cross-Coupling;
DOI:10.1002/ejoc.201400088
