1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-yn-1-ol

Base Information

• Chemical Name: 1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-yn-1-ol
• CAS No.: 941290-13-7
• Molecular Formula: C₁₈H₂₅NOSi
• Molecular Weight: 299.488
• Mol file: 941290-13-7.mol

Synonyms:1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-yn-1-ol

Chemical Property of 1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-yn-1-ol

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-yn-1-ol

There total 1 articles about 1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-yn-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-(diallylamino)benzaldehyde + trimethylsilylacetylene (1066-54-2) → 1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-yn-1-ol (941290-13-7)

Guidance literature:

trimethylsilylacetylene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.166667h;

2-(diallylamino)benzaldehyde; In tetrahydrofuran; hexane; at -78 - 20 ℃; Further stages.;

DOI:10.1002/anie.200604026

Reference yield: 90.0%

potassium hexafluorophosphate (17084-13-8) + 1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-yn-1-ol (941290-13-7) + chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II) (32993-05-8) → C53H46NP2Ru(1+)*F6P(1-)

Guidance literature:

With potassium fluoride; In tetrahydrofuran; methanol; at 20 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1002/ejic.201402678

Reference yield:

1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-yn-1-ol (941290-13-7) + acetic anhydride (108-24-7) → acetic acid 1-(2-diallylamino-phenyl)-3-trimethylsilanyl-prop-2-ynyl ester

Guidance literature:

With dmap; triethylamine; at 20 ℃; for 1h;

DOI:10.1002/anie.200604026

upstream raw materials:

trimethylsilylacetylene