(2-Bromophenyl)(imino)methyl-lambda6-sulfanone

Base Information

• Chemical Name: (2-Bromophenyl)(imino)methyl-lambda6-sulfanone
• CAS No.: 833459-47-5
• Molecular Formula: C₇H₈BrNOS
• Molecular Weight: 234.117
• European Community (EC) Number: 824-915-7
• ChEMBL ID: CHEMBL4562625
• Nikkaji Number: J2.134.343I
• Mol file: 833459-47-5.mol

Synonyms:833459-47-5;(2-bromophenyl)(imino)methyl-lambda6-sulfanone;S-Methyl-S-(2-bromophenyl)sulfoximine;(2-bromophenyl)-imino-methyl-oxo-lambda6-sulfane;1-bromo-2-(S-methylsulfonimidoyl)benzene;CHEMBL4562625;GS0094;MFCD28968129;AKOS037621952;(2-Bromophenyl)(imino)methyl-sulfanone;AT10713;AT11347;WS-03173;(2-bromophenyl)(imino)methyl-??-sulfanone;(2-Bromophenyl)(imino)(methyl)-l6-sulfanone;EN300-209489;(2-BROMOPHENYL)(IMINO)(METHYL)-LAMDA6-SULFANONE

Chemical Property of (2-Bromophenyl)(imino)methyl-lambda6-sulfanone

Chemical Property:

• XLogP3: 3.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 232.95100
• Heavy Atom Count: 11
• Complexity: 235

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CS(=N)(=O)C1=CC=CC=C1Br

Technology Process of (2-Bromophenyl)(imino)methyl-lambda6-sulfanone

There total 5 articles about (2-Bromophenyl)(imino)methyl-lambda6-sulfanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2-bromo-1-(methylsulfanyl)benzene (19614-16-5) → (2-bromophenyl)(imino)(methyl)-λ6-sulfanone (833459-47-5)

Guidance literature:

With para-iodoanisole; ammonium acetate; tetrabutylammonium acetate; tert-butylammonium hexafluorophosphate(V); In methanol; at 25 ℃; Electrolysis;

DOI:10.1002/cssc.202101002

Reference yield: 76.0%

N-(2,2,2-trifluoroethyloxycarbonyl)-2-bromophenyl methyl sulfoximine → (2-bromophenyl)(imino)(methyl)-λ6-sulfanone (833459-47-5)

Guidance literature:

With sulfuric acid; In water; at 110 ℃; for 2h;

DOI:10.1002/adsc.201300766

Reference yield: 70.0%

1-bromo-2-(methylsulfinyl)benzene (126218-83-5,146235-11-2,7321-58-6) → (2-bromophenyl)(imino)(methyl)-λ6-sulfanone (833459-47-5)

Guidance literature:

With 1,10-Phenanthroline; O-(4-nitrobenzoyl)hydroxylammonium trifluoromethanesulfonate; iron(II) sulfate; In acetonitrile; at 30 ℃; for 48h; Inert atmosphere; Sealed tube;

DOI:10.1002/anie.201710498

upstream raw materials:

1-bromo-2-(methylsulfinyl)benzene

o-bromothiophenol

2-bromo-1-(methylsulfanyl)benzene

Downstream raw materials:

S-(2-aminophenyl)-S-methylsulfoximine