(E)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

Base Information

Chemical Name:(E)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
CAS No.:1147459-18-4
Molecular Formula:C₁₈H₂₁BN₂
Molecular Weight:276.189
Hs Code.:

Synonyms:(E)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

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Chemical Property of (E)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

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Technology Process of (E)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

There total 3 articles about (E)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 57002-01-4,37490-33-8
(E)-(2-cyclohexylvinyl)boronic acid

: 479-27-6
naphthalene-1,8-diamine

: 1147459-18-4
(E)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

Guidance literature:: With 1H-imidazole; iron(III) chloride hexahydrate; In water; acetonitrile; at 20 ℃; for 24h; Inert atmosphere; Schlenk technique;
DOI:10.1002/anie.202103435

Reference yield: 80.0%

: 931-48-6
2-cyclohexylacetylene

: 5656-71-3
2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

: (Z)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

: 1147459-18-4
(E)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

: 1147459-75-3
C₁₈H₂₁BN₂

Guidance literature:: With [IrCl(COD)]2; bis[2-(diphenylphosphino)phenyl] ether; In dichloromethane; at 25 ℃; for 2h; optical yield given as %de; Inert atmosphere;
DOI:10.1021/ol9003096

Reference yield:

: 931-48-6
2-cyclohexylacetylene

: 1147459-18-4
(E)-2-(2-cyclohexylvinyl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine

Guidance literature:: Multi-step reaction with 2 steps

1.1: dichloromethane / 4 h / 0 - 20 °C

1.2: 0 - 20 °C

2.1: toluene / 2 h / 110 °C / Molecular sieve

In dichloromethane; toluene;
DOI:10.1021/jacs.5b09773